[m x n] Metal Ion Arrays Templated by Coordination Cages

被引：72
作者：
Osuga, Takafumi
Murase, Takashi
Ono, Kosuke
Yamauchi, Yoshihiro
Fujita, Makoto [1 ]
机构：
[1] Univ Tokyo, Sch Engn, Dept Appl Chem, Bunkyo Ku, Tokyo 1138656, Japan
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2010年 / 132卷 / 44期
关键词：
CRYSTAL-STRUCTURE; DISCRETE STACKING; COMPLEXES; PLATINUM; CLUSTER; DIANIONS; CHAINS; SERIES;
D O I：
10.1021/ja108367j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Three-dimensional m x n arrays of metal ion clusters can be assembled as aromatic stacks of planar polynuclear metal complexes within columnar coordination cages. The polynuclear complexes and cage height program the final array structures of the metal ion clusters. Cyclic trinuclear Au(I) complexes (m = 3) assembled into trigonal prismatic arrays (n = 1-3) within the cages and the array structures were clearly shown by X-ray crystallographic analysis. A silver-sandwiched hetero-Au-3-Ag-Au-3 cluster was also prepared by treating a hexanuclear Au-3-Au-3 cluster with Ag(I) ion.
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收藏
页码：15553 / 15555
页数：3
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