Synthesis and characterization of phthalocyanine-based soluble light-harvesting CIGS complex

被引：6
作者：
Chen, Yu
Zhuang, Xiaodong
Zhang, Weian
Liu, Ying
Lin, Ying
Yan, Aixia
Araki, Yasuyuki
Ito, Osamu
机构：
[1] E China Univ Sci & Technol, Dept Chem, Adv Mat Lab, Shanghai 200237, Peoples R China
[2] Beijing Inst Chem Technol, Dept Pharmaceut Engn, State Key Lab Chem Resource Engn, Beijing 100029, Peoples R China
[3] Tohoku Univ, Inst Multidisciplinary Res Adv Mat, Sendai, Miyagi 9808577, Japan
来源：
CHEMISTRY OF MATERIALS | 2007年 / 19卷 / 22期
关键词：
D O I：
10.1021/cm0713172
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
An easy and versatile solution-based route for the synthesis of a new phthalocyanine-based light-harvesting material PCIGS [Cu-2(tBu(4)PcGa)(tBu(4)PCIn)S2TPP2] is described. This material is prepared through a one-pot reaction of tBu(4)PcM-Cl (M = Ga, In), CuI, and [(CH3)(3)Si](2)S in the presence of triphenyl phosphine. In contrast to the dilute solution, the linear absorption coefficient of PCIGS complex in the solid state (alpha(0) = 145.35 cm(-1)) is about 150 times greater than the dilute solution (alpha(0) = 0.95 cm(-1)) under the conditions of the study. The molecular structure of this material is proposed on the basis of the extended X-ray absorption fine structure spectroscopy.
引用
收藏
页码：5256 / 5261
页数：6
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