Synthesis of nano-particles of anatase-TiO2 and preparation of its optically transparent film in PVA

被引：138

作者：

Khanna, P. K. ^{[1
]}

Singh, Narendra ^{[1
]}

Charan, Shobhit ^{[1
]}

机构：

[1] Ctr Mat Elect Technol, Nanosci Grp, Pune 411008, Maharashtra, India

来源：

MATERIALS LETTERS | 2007年 / 61卷 / 25期

关键词：

Anatase-TiO2; nano-particles; surfactants; sol-gel; optical studies; XRD;

D O I：

10.1016/j.matlet.2007.03.064

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Anatase-TiO2 nano-particles have been synthesized by using long-carbon chain carboxylic acid and titanium tetrachloride (TiCl4). As-prepared powder has been calcined at 500 degrees C to obtain highly crystalline TiO2. Broad X-ray diffraction (XRD) pattern of as-prepared as well as calcined powder showed all prominent peaks for tetragonal crystal structure representing anatase-TiO2. The particle diameter by applying Scherrer formula was found to be about 20 nm. It was possible to load as-prepared particles in poly vinyl alcohol (PVA) for optical studies. Optically transparent film showed sharp absorption band for TiO2 nano-particles at similar to 300 nm. Photoluminescence (PL) studies of the solution showed emission wavelength at about 330 nm. Transmission electron microscopy (TEM) and selected area electron diffraction (SAED) revealed that the particles in the film have uniform distribution and even for the powder no agglomeration was observed. Thermal analysis (TGA) showed that the stability of host polymer is enhanced. FTIR spectra showed presence of carboxylate functional group in the powder. (c) 2007 Elsevier B.V. All fights reserved.

引用

页码：4725 / 4730

页数：6

共 20 条

[1]

Baek SY, 2005, B KOREAN CHEM SOC, V26, P1333

[2] Direct synthesis of nanocrystalline silver from the reaction between silver carboxylates and n-trioctylphosphine [J].

Charan, Shobhit ;

Singh, Narendra ;

Khanna, P. K. ;

Patil, K. R. .

JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2006, 6 (07) :2095-2102

[3]

Cheon IC, 2003, B KOREAN CHEM SOC, V24, P1535

[4] HETEROGENEOUS PHOTOCATALYSIS [J].

FOX, MA ;

DULAY, MT .

CHEMICAL REVIEWS, 1993, 93 (01) :341-357

[5] ELECTROCHEMICAL PHOTOLYSIS OF WATER AT A SEMICONDUCTOR ELECTRODE [J].

FUJISHIMA, A ;

HONDA, K .

NATURE, 1972, 238 (5358) :37-+

[6] Photoelectrochemical cells [J].

Grätzel, M .

NATURE, 2001, 414 (6861) :338-344

[7] CONTROLLING CRYSTALLINITY DURING PROCESSING OF NANOCRYSTALLINE TITANIA [J].

HAGUE, DC ;

MAYO, MJ .

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1994, 77 (07) :1957-1960

[8] ENVIRONMENTAL APPLICATIONS OF SEMICONDUCTOR PHOTOCATALYSIS [J].

HOFFMANN, MR ;

MARTIN, ST ;

CHOI, WY ;

BAHNEMANN, DW .

CHEMICAL REVIEWS, 1995, 95 (01) :69-96

[9] Hydrothermal synthesis of rutile TiO2 nanoparticles using hydroxyl and carboxyl group-containing organics as modifiers [J].

Jiang, Benpeng ;

Yin, Hengbo ;

Jiang, Tingshun ;

Jiang, Yinhua ;

Feng, Hui ;

Chen, Kangmin ;

Zhou, Weiping ;

Wada, Yuji .

MATERIALS CHEMISTRY AND PHYSICS, 2006, 98 (2-3) :231-235

[10]

Kang MG, 2004, B KOREAN CHEM SOC, V25, P742

← 1 2 →