Open lanthanide-organic frameworks with intertwined double and triple helical structures

被引：43
作者：
Qin, C [1 ]
Wang, XL [1 ]
Wang, EB [1 ]
Xu, L [1 ]
机构：
[1] NE Normal Univ, Dept Chem, Inst Polyoxometalate Chem, Changchun 130024, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2005年 / 8卷 / 08期
基金：
中国国家自然科学基金;
关键词：
helix; hydrothermal reaction; lanthanide; luminescence;
D O I：
10.1016/j.inoche.2005.04.019
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two new three-dimensional lanthanide coordination complexes, [Ln(2)(IDC)(2)(H2O)(3)] center dot 1.5H(2)O (Ln = Sm (1), Eu (2), IDC = 4,5-imidazoledicarboxylate), have been prepared by hydrothermal reaction of Ln(2)O(3), H3IDC at 140 degrees C and characterized by single-crystal X-ray diffraction analysis. To our knowledge, they represent the first examples of having intertwined lanthanide double and triple helical motifs and nanosized tubular channels. In addition, compound 2 exhibit red photoluminescence at room temperature. (C) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码：669 / 672
页数：4
相关论文
共 33 条
  • [1] Zinc saccharate: A robust, 3D coordination network with two types of isolated, parallel channels, one hydrophilic and the other hydrophobic
    Abrahams, BF
    Moylan, M
    Orchard, SD
    Robson, R
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (16) : 1848 - 1851
  • [2] Biradha K, 2000, ANGEW CHEM INT EDIT, V39, P3843, DOI 10.1002/1521-3773(20001103)39:21<3843::AID-ANIE3843>3.0.CO
  • [3] 2-#
  • [4] Bourne SA, 2001, ANGEW CHEM INT EDIT, V40, P2111, DOI 10.1002/1521-3773(20010601)40:11<2111::AID-ANIE2111>3.0.CO
  • [5] 2-F
  • [6] A neutral 3D copper coordination polymer showing 1D open channels and the first interpenetrating NbO-type network
    Bu, XH
    Tong, ML
    Chang, HC
    Kitagawa, S
    Batten, SR
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (02) : 192 - 195
  • [7] Lanthanide-containing molecular and supramolecular polymetallic functional assemblies
    Bünzli, JCG
    Piguet, C
    [J]. CHEMICAL REVIEWS, 2002, 102 (06) : 1897 - 1928
  • [8] A route to high surface area, porosity and inclusion of large molecules in crystals
    Chae, HK
    Siberio-Pérez, DY
    Kim, J
    Go, Y
    Eddaoudi, M
    Matzger, AJ
    O'Keeffe, M
    Yaghi, OM
    [J]. NATURE, 2004, 427 (6974) : 523 - 527
  • [9] Cheetham AK, 1999, ANGEW CHEM INT EDIT, V38, P3268, DOI 10.1002/(SICI)1521-3773(19991115)38:22<3268::AID-ANIE3268>3.0.CO
  • [10] 2-U
1234