Reagent and Catalyst Design for Asymmetric Hypervalent Iodine Oxidations

被引：98
作者：
Berthiol, Florian [1 ]
机构：
[1] Univ Grenoble 1, Dept Chim Mol SERCO, ICMG FR 2607, UMR 5250, F-38041 Grenoble 9, France
来源：
SYNTHESIS-STUTTGART | 2015年 / 47卷 / 05期
关键词：
hypervalent iodine; asymmetric transformations; homogeneous organocatalysis; oxidations; carbon-carbon bond formations; carbon-heteroatom bond formations; ALPHA-FUNCTIONALIZATION; PHENOL DEAROMATIZATION; ORGANOIODINE CATALYSTS; DIARYLIODONIUM SALTS; KETONES; SPIROLACTONIZATION; DIAMINATION; SULFOXIDES; CHEMISTRY; SULFIDES;
D O I：
10.1055/s-0034-1379892
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
In this review are compiled the different possible transformations using environmentally benign chiral hypervalent iodine reagents and catalysts. Herein is presented an overview of asymmetric oxidation of sulfides to sulfoxides, oxidation of alkenes, -functionalization of carbonyl compounds and dearomatization reactions. 1 Introduction 2 Chiral Hypervalent Iodine Reagents 3 Oxidation of Sulfides to Sulfoxides 4 Oxidation of Alkenes 5 -Functionalization of Carbonyl Compounds 6 Dearomatization Reactions 7 Conclusion
引用
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页码：587 / 603
页数：17
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