Mechanochemically activated synthesis of zirconium carbide nanoparticles at room temperature: A simple route to prepare nanoparticles of transition metal carbides

被引：59

作者：

Xiang, J. Y. ^{[1
]}

Liu, S. C. ^{[1
]}

Hu, W. T. ^{[1
]}

Zhang, Y. ^{[1
]}

Chen, C. K. ^{[1
]}

Wang, P. ^{[1
]}

He, J. L. ^{[1
]}

Yu, D. L. ^{[1
]}

Xu, B. ^{[1
]}

Lu, Y. F. ^{[2
]}

Tian, Y. J. ^{[1
]}

Liu, Z. Y. ^{[1
]}

机构：

[1] Yanshan Univ, State Key Lab Metastable Mat Sci & Technol, Qinhuangdao 066004, Peoples R China

[2] NW Inst Nonferrous Met Res, Xian 710016, Shaanxi, Peoples R China

来源：

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY | 2011年 / 31卷 / 08期

关键词：

Milling; Grain size; Spark plasma sintering; Carbides; Solid liquid reaction; HYDRIDE FORMATION; NITRIDE POWDERS; TITANIUM; IRON; ZR; ALUMINUM; SYSTEM;

D O I：

10.1016/j.jeurceramsoc.2011.01.022

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Mechanically activated syntheses of zirconium carbides (ZrCx) nanoparticles have been performed via ball milling of Zr powder with toluene. It has been found that the milling time can be used to tune the ratio x of C to Zr. The spark plasma sintering of the ZrCx nanoparticles has shown that the densification can be achieved at a considerably reduced temperature of 1200 degrees C. This ball milling procedure has been tried to successfully synthesize the nanoparticles of WCx, TiCx, and NbCx, demonstrating that it is a potential route to prepare the nanoparticles of transition metal carbides. (C) 2011 Elsevier Ltd. All rights reserved.

引用

页码：1491 / 1496

页数：6

共 45 条

[1] LATTICE-PARAMETERS AND THERMAL-EXPANSION OF TI(CXN1-X), ZR(CXN1-X), HF(CXN1-X) AND TIN1-X FROM 298-K TO 1473-K AS INVESTIGATED BY HIGH-TEMPERATURE X-RAY-DIFFRACTION
AIGNER, K
LENGAUER, W
RAFAJA, D
ETTMAYER, P
[J]. JOURNAL OF ALLOYS AND COMPOUNDS, 1994, 215 (1-2) : 121 - 126
[2] ENTHALPY OF FORMATION OF ZIRCONIUM CARBIDE
BAKER, FB
STORMS, EK
HOLLEY, CE
[J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1969, 14 (02) : 244 - &
[3] On the mechanism of carbothermal reduction processes of TiO2 and ZrO2
Berger, LM
Gruner, W
Langholf, E
Stolle, S
[J]. INTERNATIONAL JOURNAL OF REFRACTORY METALS & HARD MATERIALS, 1999, 17 (1-3) : 235 - 243
[4] Mechanical activation of structural and chemical transformations in a ZR-C-H system in two stages
Borchers, C
Leonov, AV
Morozova, OS
[J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2002, 106 (08) : 1843 - 1848
[5] Competitive gas-solid reactions realized by ball milling of Zr in ammonia gas
Chen, Y
Williams, JS
[J]. JOURNAL OF MATERIALS RESEARCH, 1996, 11 (06) : 1500 - 1506
[6] ENTHALPIES OF FORMATION OF ZIRCONIUM DIHYDRIDE AND ZIRCONIUM DIDEUTERIDE
FREDRICKSON, DR
HUBBARD, WN
NUTTALL, RL
FLOTOW, HE
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1963, 67 (07) : 1506 - &
[7] MECHANICAL ALLOYING
GILMAN, PS
BENJAMIN, JS
[J]. ANNUAL REVIEW OF MATERIALS SCIENCE, 1983, 13 : 279 - 300
[8] Gusev A. I., 2000, Physics-Uspekhi, V43, P1, DOI 10.1070/PU2000v043n01ABEH000647
[9] Hugh O., 1996, Handbook of Refractory Carbides and Nitrides
[10] CRYSTALLOGRAPHIC AND MAGNETIC-PROPERTIES OF FINE IRON NITRIDE POWDERS PREPARED BY SOLID-STATE REACTIONS BETWEEN IRON AND ORGANIC H-X(CN)-RING COMPOUNDS
KACZMAREK, WA
[J]. SCRIPTA METALLURGICA ET MATERIALIA, 1995, 33 (10-11): : 1687 - 1694

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