A fluorescent carboxamide ligand, having combined ionophore/fluorophore moieties, exhibiting "On-Off" switching toward Zn2+ ion

被引：26

作者：

Amirnasr, Mehdi ^{[1
]}

Erami, Roghayeh Sadeghi ^{[1
]}

Meghdadi, Soraia ^{[1
]}

机构：

[1] Isfahan Univ Technol, Dept Chem, Esfahan 8415683111, Iran

来源：

SENSORS AND ACTUATORS B-CHEMICAL | 2016年 / 233卷

关键词：

Carboxamide ligand; Ionophore/fluorophore; Zn2+ sensor; CHEF effect; Fluorescent probe; ZINC IONS; BENIGN SYNTHESIS; CHEMOSENSOR; PROBE; ZN(II); INHIBITORS; COMPLEXES; STRENGTH; REMOVAL; CADMIUM;

D O I：

10.1016/j.snb.2016.04.077

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A carboxamide ligand (N-(quinolin-8-yl)quinoline-2-carboxamide) (Hqcq) has been synthesized by a highly efficient procedure using the ionic liquid TBAB as an environmentally benign reaction medium. Selective "On-Off" switching behavior of the fluorescent ligand (Hqcq) in acetonitrile has been studied for Zn(II) ion. The Hqcq was weakly emissive in the absence of metal ions, but fluorescence intensity was increased significantly upon addition of two equivalent of Zn(II) ion. This enhancement was correlated to Zn(II) coordination of the qcq(-), producing an efficient chelation-enhanced fluorescence (CHEF) effect. Other interfering elements such as Cd(II) and Hg(II), show either no or slight change in the fluorescence intensity under similar experimental conditions. (C) 2016 Elsevier B.V. All rights reserved.

引用

页码：355 / 360

页数：6

共 43 条

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