Rapid removal and recovery of Pb(II) from wastewater by magnetic nanoadsorbents

被引:475
作者
Nassar, Nashaat N. [1 ]
机构
[1] Univ Calgary, Dept Chem & Petr Engn, Calgary, AB T2N 1N4, Canada
关键词
Lead; Nanoadsorbent; Iron oxide; Wastewater; Adsorption; Equilibrium; Nanoparticle; AQUEOUS-SOLUTIONS; HEAVY-METALS; ADSORPTION; LEAD; IONS; CR(VI); SORPTION; MONTMORILLONITE; NANOPARTICLES; ACCUMULATION;
D O I
10.1016/j.jhazmat.2010.08.069
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Iron oxide nanoadsorbents are cost-effective adsorbents that provide high adsorption capacity, rapid adsorption rate and simple separation and regeneration. In this study, Fe3O4 nanoadsorbents have been employed for the removal of Pb(II) ions from aqueous solutions by a batch-adsorption technique. The effects of contact time, initial concentration of Pb(II) ions, temperature, solution pH and coexisting ions on the amount of Pb(II) adsorbed have been investigated. Pb(II) adsorption was fast, and equilibrium was achieved within 30 min. The amount of Pb(II) adsorbed increased as temperature increased, suggesting an endothermic adsorption. The optimal pH value for Pb(II) adsorption was around 5.5. Furthermore. the addition of coexisting cations such as Ca2+, Ni2+. Co2+, and Cd2+ has no remarkable influence on Pb(II) removal efficiency. The adsorption equilibrium data fitted very well to Langmuir and Freundlich adsorption isotherm models. The thermodynamics of Pb(II) adsorption onto the Fe3O4 nanoadsorbents indicated that the adsorption was spontaneous, endothermic and physical in nature. The desorption and regeneration studies have proven that Fe3O4 nanoadsorbents can be employed repeatedly without impacting its adsorption capacity. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:538 / 546
页数:9
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