A Troger's base-derived microporous organic polymer: design and applications in CO2/H2 capture and hydrogenation of CO2 to formic acid

被引：91

作者：

Yang, Zhen-Zhen ^{[1
]}

Zhang, Hongye ^{[1
]}

Yu, Bo ^{[1
]}

Zhao, Yanfei ^{[1
]}

Ji, Guipeng ^{[1
]}

Liu, Zhimin ^{[1
]}

机构：

[1] Chinese Acad Sci, Inst Chem, Key Lab Colloid Interface & Thermodynam, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 07期

基金：

中国国家自然科学基金;

关键词：

CARBON-DIOXIDE; POROUS MATERIALS;

D O I：

10.1039/c4cc08295h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A Troger's base-derived microporous organic polymer (TB-MOP) was designed, which could adsorb CO2 and coordinate with a Ru(III) complex. The resultant TB-MOP-Ru showed good CO2 and H-2 adsorbing performances, and high efficiency for catalysing hydrogenation of CO2 to HCOOH with a turnover number up to 2254 at 40 degrees C.

引用

页码：1271 / 1274

页数：4

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