Gas response control through structural and chemical modification of metal oxide films: state of the art and approaches

被引:536
作者
Korotcenkov, G [1 ]
机构
[1] Tech Univ Moldova, Lab Micro & Optoelect, Kishinev 2004, Moldova
来源
SENSORS AND ACTUATORS B-CHEMICAL | 2005年 / 107卷 / 01期
关键词
tin dioxide; indium oxide; structure; modification; conductometric gas sensors;
D O I
10.1016/j.snb.2004.10.006
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
In this review the structural and physical-chemical properties of nanoscaled metal oxide films (SnO2 and In2O3), aimed for solid state chemical sensors were analyzed. It has been shown that structural factor even for nanoscaled materials is complicated conception. One has to consider not only size, but also such a parameters as crystallite shape; nanoscopic structure; crystallographic orientation of nanocrystallites planes, forming gas sensing surface; film agglomeration; phase composition; surface architecture. The methods suitable for control of these structural and physical-chemical parameters have been discussed. Results, mainly obtained during study of both SnO2 and In2O3 thin films deposited by spray pyrolysis have been used for showing an opportunity of structural engineering of metal oxides for optimization of gas sensing characteristics. (c) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:209 / 232
页数:24
相关论文
共 99 条
  • [1] [Anonymous], 1972, MECH FORMATION SUBST
  • [2] Characterization of BaSnO3-based ceramics -: Part 1.: Synthesis, processing and microstructural development
    Azad, AM
    Hon, NC
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 1998, 270 (1-2) : 95 - 106
  • [3] Fundamental and practical aspects in the design of nanoscaled SnO2 gas sensors:: a status report
    Barsan, N
    Schweizer-Berberich, M
    Göpel, W
    [J]. FRESENIUS JOURNAL OF ANALYTICAL CHEMISTRY, 1999, 365 (04): : 287 - 304
  • [4] Brinzari V, 2002, J OPTOELECTRON ADV M, V4, P147
  • [5] Morphological rank of nano-scale tin dioxide films deposited by spray pyrolysis from SnCl45H2O water solution
    Brinzari, V
    Korotcenkov, G
    Golovanov, V
    Schwank, J
    Lantto, V
    Saukko, S
    [J]. THIN SOLID FILMS, 2002, 408 (1-2) : 51 - 58
  • [6] Factors influencing the gas sensing characteristics of tin dioxide films deposited by spray pyrolysis: understanding and possibilities of control
    Brinzari, V
    Korotcenkov, G
    Golovanov, V
    [J]. THIN SOLID FILMS, 2001, 391 (02) : 167 - 175
  • [7] BRINZARI V, 2002, P INT C MICR COMP SC, V1, P336
  • [8] BRINZARI V, 1999, P SOC PHOTO-OPT INS, P186
  • [9] BRINZARI V, 2000, P SEM INT C CAS 2000, V1, P127
  • [10] Simulation of thin film gas sensors kinetics
    Brynzari, V
    Korotchenkov, G
    Dmitriev, S
    [J]. SENSORS AND ACTUATORS B-CHEMICAL, 1999, 61 (1-3): : 143 - 153