Synthesis of Symmetrical and Unsymmetrical 1,4-Dithiins by Rhodium-Catalyzed Sulfur Addition Reaction to Alkynes

被引：10
作者：
Arisawa, Mieko [1 ]
Ichikawa, Takuya [1 ]
Tanii, Saori [1 ]
Yamaguchi, Masahiko [1 ]
机构：
[1] Tohoku Univ, Grad Sch Pharmaceut Sci, Dept Organ Chem, 6-3 Aoba, Sendai, Miyagi 9808578, Japan
来源：
SYNTHESIS-STUTTGART | 2016年 / 48卷 / 18期
关键词：
sulfur; 1,4-dithiins; rhodium; addition reaction; alkynes; CONTAINING POLYMERS; ELEMENTAL SULFUR; THIANTHRENE; COMPLEXES; PLATINUM(II); INHIBITOR; SELENIUM; LIGANDS; ALKENES; KINASE;
D O I：
10.1055/s-0035-1561452
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A convenient synthetic method for 1,4-dithiins was developed using sulfur and alkynes. A rhodium complex catalyzes the addition reaction of sulfur with cyclic alkynes giving the corresponding symmetrical 1,4-dithiines under reflux conditions in 2-butanone. Unsymmetrical 1,4-dithiins are synthesized by the reaction of sulfur with dialkyl acetylenedicarboxylates in the presence of cyclic alkynes or vinyl ethers.
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收藏
页码：3107 / 3119
页数：13
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