The Properties of Thermosensitive Zwitterionic Sulfobetaine NIPAM-co-DMAAPS Polymer and the Hydrogels: The Effects of Monomer Concentration on the Transition Temperature and Its Correlation with the Adsorption Behavior

被引：4

作者：

Ningrum, Eva Oktavia ^{[1
]}

Purwanto, Agus ^{[2
]}

Rosita, Galuh Chynintya ^{[3
]}

Bagus, Asep ^{[3
]}

机构：

[1] Inst Teknol Sepuluh Nopember, Fac Vocat Studies, Dept Ind Chem Engn, Kampus ITS Sukolilo, Surabaya 60111, Indonesia

[2] Univ Sebelas Maret, Fac Engn, Dept Chem Engn, Jl Ir Sutami 36A, Surakarta 57126, Central Java, Indonesia

[3] Inst Teknol Sepuluh Nopember, Fac Ind Technol, Dept Chem Engn, Kampus ITS Sukolilo, Surabaya 60111, Indonesia

来源：

INDONESIAN JOURNAL OF CHEMISTRY | 2020年 / 20卷 / 02期

关键词：

transition temperature; thermosensitive; adsorption; HEAVY-METAL IONS; WASTE-WATER; GEL; REMOVAL; PRECIPITATION; DESORPTION;

D O I：

10.22146/ijc.41499

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The properties of N-isopropylacrylamide copolymerized with N,N-dimethyl (acrylamidopropyl)ammonium propane sulfonate [poly(NIPAM-co-DMAAPS)] prepared with various monomer ratios such as transition temperature, molecular structure, viscosity were systematically investigated in water and Zn(NO3)(2) solution. Poly(NIPAM-co-DMAAPS) in water and Zn(NO3)(2) solution exhibited a phase transition with a lower critical solution temperature (LCST). The higher ratio of NIPAM monomer in poly(NIPAM-co-DMAAPS), the lower the LCST of the polymer. Furthermore, the transition temperature of poly(NIPAM-co-DMAAPS) with a lower NIPAM concentration were not confirmed both in water nor Zn(NO3)(2) solution. The more increase the NIPAM concentration used in the preparation, the more increase the polymer viscosity. Moreover, the more increase the adsorption amount of ions onto the gel, the more increase the polymer transmittance as well.

引用

页码：324 / 335

页数：12