Efficient Synthesis of 2,3,4-Trisubstituted Quinolines via Friedlander Annulation with Nanoporous Cage-Type Aluminosilicate AlKIT-5 Catalyst

被引：10

作者：

Chauhan, S. ^{[1
]}

Chakravarti, R. ^{[1
]}

Zaidi, S. M. J. ^{[2
]}

Al-Deyab, Salem S. ^{[3
]}

Reddy, B. V. Subba ^{[1
,4
]}

Vinu, A. ^{[1
,4
]}

机构：

[1] Natl Inst Mat Sci, WPI Res Ctr, Int Ctr Mat Nanoarchitecton, Tsukuba, Ibaraki 3050044, Japan

[2] King Fahd Univ Petr & Minerals, Dept Chem Engn, Dhahran 31261, Saudi Arabia

[3] King Saud Univ, Fac Sci, Petrochem Res Chair, Dept Chem, Riyadh 11451, Saudi Arabia

[4] Indian Inst Chem Technol, NIMS IICT Mat Res Ctr, Hyderabad 500007, Andhra Pradesh, India

来源：

SYNLETT | 2010年 / 17期

关键词：

o-aminoaryl ketones; nanoporous catalysts; domino reactions; quinolines; CONJUGATED POLYMERS; DERIVATIVES; ACID; ELECTROLUMINESCENCE; INHIBITORS; ANILINES;

D O I：

10.1055/s-0030-1258575

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

2-Aminoaryl ketones undergo smooth Friedlander condensation/annulation with alpha-methyleneketones on the surface of nanoporous aluminosilicate catalyst to afford the corresponding quinoline derivatives in good yields with high selectivity due to its high surface area, large pore volume, and high acidity. The use of highly acidic and reusable AlKIT-5 catalyst makes the Friedlander annulation simple, convenient, and practical.

引用

页码：2597 / 2600

页数：4

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