Green and sustainable carbon aerogels from starch for supercapacitors and oil-water separation

被引:41
作者
Zhai, Zuozhao [1 ,2 ]
Zheng, Yuxuan [1 ,3 ]
Du, Tianmin [4 ]
Tian, Zhaoshun [4 ]
Ren, Bin [1 ,2 ]
Xu, Yuelong [1 ,2 ]
Wang, Shasha [1 ,2 ]
Zhang, Lihui [1 ,2 ]
Liu, Zhenfa [1 ,2 ]
机构
[1] Hebei Acad Sci, Inst Energy Resources, Shijiazhuang 050081, Hebei, Peoples R China
[2] Hebei Engn Res Ctr Water Saving Ind, Shijiazhuang 050081, Hebei, Peoples R China
[3] Hebei Univ Technol, Coll Chem Engn, Tianjin 300130, Peoples R China
[4] Shenzhou Engn Plast Co Ltd, Hengshui 052800, Hebei, Peoples R China
关键词
Carbon aerogels; Starch; Potassium chloride; Potassium carbonate; Supercapacitors; DOPED POROUS CARBON; HIGH-PERFORMANCE SUPERCAPACITOR; ENERGY-STORAGE; BIOMASS; CELLULOSE; WASTE; CARBONIZATION; ELECTRODE; ALGINATE; REMOVAL;
D O I
10.1016/j.ceramint.2021.04.229
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Biomass-based carbon aerogels have attracted significant research attention due to the wide range of raw material, low cost, and environmental friendliness. In this study, green and sustainable carbon aerogels have been prepared using starch as raw material. Potassium chloride and potassium carbonate have been selected as template and activator. Due to the joint action of potassium chloride and potassium carbonate, the starch-based carbon aerogels exhibit a specific surface area of 2367 m2 g-1 with ant-hole-like 3D network pore structure. The starch-based carbon aerogels have been further employed as the electrode material for supercapacitors. The specific capacitance of the carbon aerogels is 292.3 and 245 F g-1 at current densities of 1.0 and 10 A g-1, respectively. In addition, the starch-based carbon aerogels demonstrate excellent sorption ability for oil and organics as well as insignificant sorption ability for H2O, thus, indicating their potential use as optimal oil-water separation material.
引用
收藏
页码:22080 / 22087
页数:8
相关论文
共 42 条
  • [1] Starbons: New starch-derived mesoporous carbonaceous materials with tunable properties
    Budarin, Vitaly
    Clark, James H.
    Hardy, Jeffrey J. E.
    Luque, Rafael
    Milkowski, Krzysztof
    Tavener, Stewart J.
    Wilson, Ashley J.
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (23) : 3782 - 3786
  • [2] Hierarchically porous carbons with graphene incorporation for efficient supercapacitors
    Chang, Jiuli
    Gao, Zhiyong
    Liu, Xiao
    Wu, Dapeng
    Xu, Fang
    Guo, Yawen
    Guo, Yuming
    Jiang, Kai
    [J]. ELECTROCHIMICA ACTA, 2016, 213 : 382 - 392
  • [3] Nitrogen Doped Microporous Carbons with Tunable and Selective performances in Supercapacitor and Heterogeneous Catalysis
    Chang, Jiuli
    Gao, Zhiyong
    Zhao, Wenqi
    Guo, Liyan
    Chu, Meng'en
    Tang, Yadong
    Wu, Dapeng
    Xu, Fang
    Jiang, Kai
    [J]. ELECTROCHIMICA ACTA, 2016, 190 : 912 - 922
  • [4] Gelatin-derived nitrogen-doped porous carbon via a dual-template carbonization method for high performance supercapacitors
    Chen, Xiang Ying
    Chen, Chong
    Zhang, Zhong Jie
    Xie, Dong Hua
    [J]. JOURNAL OF MATERIALS CHEMISTRY A, 2013, 1 (36) : 10903 - 10911
  • [5] Chen Z., 2020, ADV FUNCT MATER
  • [6] Facile synthesis of cellulose-based carbon with tunable N content for potential supercapacitor application
    Chen, Zehong
    Peng, Xinwen
    Zhang, Xiaoting
    Jing, Shuangshuang
    Zhong, Linxin
    Sun, Runcang
    [J]. CARBOHYDRATE POLYMERS, 2017, 170 : 107 - 116
  • [7] Biomass-Derived Carbon Fiber Aerogel as a Binder-Free Electrode for High-Rate Supercapacitors
    Cheng, Ping
    Li, Ting
    Yu, Hang
    Zhi, Lei
    Liu, Zonghuai
    Lei, Zhibin
    [J]. JOURNAL OF PHYSICAL CHEMISTRY C, 2016, 120 (04) : 2079 - 2086
  • [8] A sustainable approach to hierarchically porous carbons from tannic acid and their utilization in supercapacitive energy storage systems
    Diez, Noel
    Ferrero, Guillermo A.
    Sevilla, Marta
    Fuertes, Antonio B.
    [J]. JOURNAL OF MATERIALS CHEMISTRY A, 2019, 7 (23) : 14280 - 14290
  • [9] Nitrogen-Enriched Carbon Nanofiber Aerogels Derived from Marine Chitin for Energy Storage and Environmental Remediation
    Ding, Beibei
    Huang, Shasha
    Pang, Kai
    Duan, Yongxin
    Zhang, Jianming
    [J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2018, 6 (01): : 177 - 185
  • [10] Hierarchically porous carbon derived from polymers and biomass: effect of interconnected pores on energy applications
    Dutta, Saikat
    Bhaumik, Asim
    Wu, Kevin C. -W.
    [J]. ENERGY & ENVIRONMENTAL SCIENCE, 2014, 7 (11) : 3574 - 3592