Tf2O-Promoted Trifluoromethythiolation of Various Arenes Using NaSO2CF3

被引：24
作者：
Liu, Jie [1 ]
Zhao, Xiaochun [1 ]
Jiang, Lvqi [1 ]
Yi, Wenbin [1 ]
机构：
[1] Nanjing Univ Sci & Technol, Chem Enginering Coll, 200 Xiao Ling Wei St, Nanjing, Jiangsu, Peoples R China
来源：
ADVANCED SYNTHESIS & CATALYSIS | 2018年 / 360卷 / 20期
基金：
中国国家自然科学基金;
关键词：
Trifluoromethylthiolation; sodium trifluoromethanesulfinate; trifluoromethanesulfonic anhydride; arenes; COPPER-CATALYZED TRIFLUOROMETHYLTHIOLATION; ELECTROPHILIC TRIFLUOROMETHYLTHIOLATION; BORONIC ACIDS; SILVER(I) TRIFLUOROMETHANETHIOLATE; ARYL; MILD; CF3SO2NA; TRIFLUOROMETHANESULFANYLATION; REAGENTS; SULFIDES;
D O I：
10.1002/adsc.201800702
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
A sulfonic anhydride-promoted direct trifluoromethylthiolation using NaSO2CF3 has been developed. The simple and practical strategy enabled the direct introduction of SCF3 moiety into unexplored arene scaffolds under reductant- and metal-free condition at room temperature.
引用
收藏
页码：4012 / 4016
页数：5
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