SYNTHESIS AND CHARACTERIZATION OF CuInS2 NANOPARTICLES AS POTENTIAL CANDIDATES FOR PHOTOCATALYST AND PHOTOVOLTAIC MATERIALS

被引:0
作者
Rajendar, V. [1 ,5 ]
Dayakar, T. [2 ]
Satish, B. [2 ]
Subramanyam, K. [3 ]
Prashanthi, Y. [4 ]
机构
[1] Yeungnam Univ, Dept Elect Engn, Gyongsan 38541, South Korea
[2] Jawaharlal Nehru Technol Univ, Ctr Nano Sci & Technol, Hyderabad, Andhra Pradesh, India
[3] Raghu Engn Coll, Dept Phys, Vizag, India
[4] Mahatma Gandhi Univ, Dept Chem, Nalgonda, Telangana, India
[5] BV Raju Inst Technol, Dept Phys, Medak, Telangana, India
来源
CHALCOGENIDE LETTERS | 2016年 / 13卷 / 10期
关键词
Solar cell; Nanoparticles; Photocatalytic; Microwave-assisted co-precipitation; MICROWAVE-ASSISTED SYNTHESIS; OPTICAL-PROPERTIES; THIN-FILMS; CHEMISTRY; GROWTH; ROUTE;
D O I
暂无
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Nanostructured CuInS2 (CIS) as the absorption layer of solar cells prepared through microwave assisted co-precipitation technique. Obtained dark brown CuInS2 nanoparticles via microwave irradiation by mixture of Cu(SO4)(2). H2O and InCl3 and sulfide sources, such as thioacetamide (TAA), thiourea and l-cysteine, at a 1: 1: 2 molar ratio, propylene glycol used as a solvent. In the process, the affect of sulfide source on the nano particle morphology and photovoltaic solar cell yield were investigated. The properties studied through X-ray diffraction (XRD), Photoluminescence spectroscopy (PL), Energy dispersive X-ray spectroscopy (EDS), Scanning electron microscopy (SEM). CuInS2 tetragonal shape confirmed with the XRD analysis. The band gap of CuInS2 was 2.2eV. For the solar cell tests, a CdS film deposited on the CIS thin film using the Doctor's blade method. By using methyl orange (MO) the photocatalytic degradation activity examined under the visible light irradiation (lambda > 400 nm).
引用
收藏
页码:467 / 475
页数:9
相关论文
共 48 条
[1]   Synthesis and characterization of CuInS2 microsphere under controlled reaction conditions and its application in low-cost solar cells [J].
Amiri, Omid ;
Salavati-Niasari, Masoud ;
Sabet, Mohammad ;
Ghanbari, Davood .
MATERIALS SCIENCE IN SEMICONDUCTOR PROCESSING, 2013, 16 (06) :1485-1494
[2]   Phase-Selective Synthesis of CuInS2 Nanocrystals [J].
Batabyal, Sudip K. ;
Tian, Lu ;
Venkatram, N. ;
Ji, Wei ;
Vittal, Jagadese J. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (33) :15037-15042
[3]   Microwave chemistry for inorganic nanomaterials synthesis [J].
Bilecka, Idalia ;
Niederberger, Markus .
NANOSCALE, 2010, 2 (08) :1358-1374
[4]   Kinetic and Thermodynamic Aspects in the Microwave-Assisted Synthesis of ZnO Nanoparticles in Benzyl Alcohol [J].
Bilecka, Idalia ;
Elser, Pierre ;
Niederberger, Markus .
ACS NANO, 2009, 3 (02) :467-477
[5]  
Bogdal D., 2007, MICROWAVE ENHANCED P
[7]   Solid-state and solution phase metathetical synthesis of copper indium chalcogenides [J].
Carmalt, CJ ;
Morrison, DE ;
Parkin, IP .
JOURNAL OF MATERIALS CHEMISTRY, 1998, 8 (10) :2209-2211
[8]   Nanocrystalline chalcopyrite materials (CuInS2 and CuInSe2) via low-temperature pyrolysis of molecular single-source precursors [J].
Castro, SL ;
Bailey, SG ;
Raffaelle, RP ;
Banger, KK ;
Hepp, AF .
CHEMISTRY OF MATERIALS, 2003, 15 (16) :3142-3147
[9]   THE PREPARATION OF CDS PARTICLES IN SILICA GLASSES BY A SOL-GEL METHOD [J].
CORDONCILLO, E ;
ESCRIBANO, P ;
MONROS, G ;
TENA, MA ;
ORERA, VM ;
CARDA, J .
JOURNAL OF SOLID STATE CHEMISTRY, 1995, 118 (01) :1-5
[10]   Synthesis, Characterization, and Growth Mechanism of n-Type CuInS2 Colloidal Particles [J].
Courtel, Fabrice M. ;
Paynter, Royston W. ;
Marsan, Benoit ;
Morin, Mario .
CHEMISTRY OF MATERIALS, 2009, 21 (16) :3752-3762