Stability of nanocomposites of poly(ε-caprolactone) with tungsten trioxide

被引:12
作者
Machado, Ana V. [1 ]
Botelho, Gabriela [2 ]
Manuela Silva, M. [2 ]
Neves, Isabel Correia [2 ]
Fonseca, Antonio M. [2 ]
机构
[1] Univ Minho, Inst Polymers & Composites I3N, P-4800058 Guimaraes, Portugal
[2] Univ Minho, Ctr Quim, Dept Quim, P-4710057 Braga, Portugal
关键词
Nanocomposite; WO(3); Poly(epsilon-caprolactone); Photodegradation; Thermal stability; PHOTOCATALYTIC DEGRADATION; CRYSTALLIZATION BEHAVIOR; POLYCAPROLACTONE; PHOTODEGRADATION; DEGRADABILITY; PERFORMANCE; COMPOSITES; COPOLYMERS; BLENDS; DSC;
D O I
10.1007/s10965-011-9580-z
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Nanocomposites of poly(epsilon-caprolactone) (PCL) and tungsten trioxide (WO(3)) were prepared by solvent casting using 5 and 10% of WO(3) nanoparticles. The nanocomposites were characterized using several analytical techniques such as XRD, SEM, thermal analysis (TGA and DSC), spectroscopic methods (FTIR and UV/Vis) to gather information on the modifications introduced by WO(3). Photodegradation of PCL/WO(3) nanocomposites was studied exposing the samples to a Xenon lamp, which simulates the UV spectrum of the sun. The results obtained showed that due to the incorporation of WO(3) nanoparticles, the nanocomposites exhibit higher thermal stability together with higher photodegradation efficiency.
引用
收藏
页码:1743 / 1749
页数:7
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