Investigation of inhibitors efficacy in wax deposition mitigation using a laboratory scale flow loop

被引:96
作者
Chi, Yuandao [1 ]
Daraboina, Nagu [1 ]
Sarica, Cem [1 ]
机构
[1] Univ Tulsa, Paraffin Deposit Projects, McDougal Sch Petr Engn, 2450 East Marshall, Tulsa, OK 74110 USA
关键词
wax deposition; paraffin inhibitor; flow loop; efficacy; FUSED CHEMICAL-REACTIONS; VINYL-ACETATE COPOLYMERS; CRUDE-OIL; PARAFFIN DEPOSITION; TUBULAR REACTORS; POUR POINT; CRYSTALLIZATION; MECHANISM; TEMPERATURE; REMEDIATION;
D O I
10.1002/aic.15307
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Statistically reliable wax inhibition experimental data was obtained by utilizing the newly built laboratory scale flow loop. The comb-shaped inhibitors are found more effective in decreasing the thickness compared to the linear inhibitor under the same conditions. Moreover, this becomes more predominant as the chain length of inhibitors increases. Interestingly, even though all the inhibitors decreased the deposit thickness, the wax content increased significantly. Besides, the longer chain length (PI-B) of the inhibitor results in a higher wax content. Since the combination of growth and aging influenced by the presence of inhibitor significantly, paraffin inhibition efficiency (PIE) based on the wax mass was proposed to quantitatively assess the inhibitors. Based on the PIE, PI-B, and PI-C have more inhibition efficiency than PI-A. Therefore, when selecting wax inhibitor, one should be aware about the strength of the deposit gel in addition to the reduction of the deposit mass. (c) 2016 American Institute of Chemical Engineers AIChE J, 62: 4131-4139, 2016
引用
收藏
页码:4131 / 4139
页数:9
相关论文
共 44 条
[1]  
[Anonymous], SPE SAUD AR SECT YOU
[2]  
[Anonymous], THESIS
[3]  
[Anonymous], 2014, 24 INT OC POL ENG C
[4]   An evaluation of the performance of selected wax inhibitors on paraffin deposition of Nigerian crude oils [J].
Bello, OO ;
Fasesan, SO ;
Teodoriu, C ;
Reinicke, KM .
PETROLEUM SCIENCE AND TECHNOLOGY, 2006, 24 (02) :195-206
[5]   SYNTHESIS AND EVALUATION OF ALKYL FUMARATE VINYL-ACETATE COPOLYMERS IN COMBINATION WITH ALKYL ACRYLATES AS FLOW IMPROVERS FOR BORHOLLA CRUDE-OIL [J].
BORTHAKUR, A ;
LASKAR, NC ;
MAZUMDAR, RK ;
RAO, KV ;
SUBRAHMANYAM, B .
JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY, 1995, 62 (01) :75-80
[6]  
COBERLY CJ, 1942, Patent No. 2303823
[7]   Computer-assisted design of oil additives: hydrate and wax inhibitors [J].
Duffy, DM ;
Moon, C ;
Rodger, PM .
MOLECULAR PHYSICS, 2004, 102 (02) :203-210
[8]   Modeling the activity of wax inhibitors: A case study of poly(octadecyl acrylate) [J].
Duffy, DM ;
Rodger, PM .
JOURNAL OF PHYSICAL CHEMISTRY B, 2002, 106 (43) :11210-11217
[9]   Modified maleic anhydride-co-octadecene copolymers as flow improver for waxy Egyptian crude oil [J].
El-Ghazawy, Rasha A. ;
Atta, Ayman M. ;
Kabel, Khalid I. .
JOURNAL OF PETROLEUM SCIENCE AND ENGINEERING, 2014, 122 :411-419
[10]   Crude oil wax crystallization.: The effect of heavy n-paraffins and flocculated asphaltenes [J].
García, MD .
ENERGY & FUELS, 2000, 14 (05) :1043-1048