Assessment of Ball Milling as a Compounding Technique to Develop Nanocomposites of Poly(3-Hydroxybutyrate-co-3-Hydroxyvalerate) and Bacterial Cellulose Nanowhiskers

被引：23

作者：

Ambrosio-Martin, Jesus ^{[1
]}

Jose Fabra, Maria ^{[1
]}

Lopez-Rubio, Amparo ^{[1
]}

Gorrasi, Giuliana ^{[2
]}

Sorrentino, Andrea ^{[3
]}

Lagaron, Jose M. ^{[1
]}

机构：

[1] IATA CSIC, Novel Mat & Nanotechnol Grp, Avda Agustin Escardino 7, Valencia 46980, Spain

[2] Univ Salerno, Dept Ind Engn, Via Giovanni Paolo II 132, Salerno, Italy

[3] Natl Res Council CNR, IPCB, Ple Enrico Fermi 1, I-80055 Portici, Italy

来源：

JOURNAL OF POLYMERS AND THE ENVIRONMENT | 2016年 / 24卷 / 03期

关键词：

Polyhydroxyalkanoates; Bacterial cellulose nanowhiskers; Bacterial cellulose nanocrystals; Oxygen barrier; Ball milling; HYDROCHLORIC-ACID HYDROLYSIS; THERMAL-PROPERTIES; CRYSTALLIZATION KINETICS; MELTING BEHAVIOR; CARBON NANOTUBE; PHASE-CHANGE; NANOCRYSTALS; DISPERSION; MORPHOLOGY; BARRIER;

D O I：

10.1007/s10924-016-0767-6

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

The aim of this study was the assessment of high energy ball milling technique to develop poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) nanocomposites containing bacterial cellulose nanowhiskers (BCNW). Crystallization behaviour of PHBV/BCNW nanocomposites was studied under non-isothermal and isothermal conditions using differential scanning calorimetry. The changes in PHBV crystalline structure were also studied using X-ray diffraction. The results confirmed that BCNW acted as nucleating agents and, hence, favored the crystallization of the PHBV. The oxygen permeability of the nanocomposites was reduced by 22 % when compared to that of the neat PHBV. This work provides a new insight into the development of polyhydroxyalkanoate composites by means of the high energy ball milling technique.

引用

页码：241 / 254

页数：14

共 59 条

[31] The morphology and thermal properties of multi-walled carbon nanotube and poly(hydroxybutyrate-co-hydroxyvalerate) composite [J].

Lai, MD ;

Li, J ;

Yang, J ;

Liu, JJ ;

Tong, X ;

Cheng, HM .

POLYMER INTERNATIONAL, 2004, 53 (10) :1479-1484

[32] On the extraction of cellulose nanowhiskers from food by-products and their comparative reinforcing effect on a polyhydroxybutyrate-co-valerate polymer [J].

Martinez-Sanz, Marta ;

Vicente, Antonio A. ;

Gontard, Nathalie ;

Lopez-Rubio, Amparo ;

Lagaron, Jose M. .

CELLULOSE, 2015, 22 (01) :535-551

[33] Characterization of polyhydroxyalkanoates synthesized from microbial mixed cultures and of their nanobiocomposites with bacterial [J].

Martinez-Sanz, Marta ;

Villano, Marianna ;

Oliveira, Catarina ;

Albuquerque, Maria G. E. ;

Majone, Mauro ;

Reis, Maria ;

Lopez-Rubio, Amparo ;

Lagaron, Jose M. .

NEW BIOTECHNOLOGY, 2014, 31 (04) :364-376

[34] Nanocomposites of ethylene vinyl alcohol copolymer with thermally resistant cellulose nanowhiskers by melt compounding (I): Morphology and thermal properties [J].

Martinez-Sanz, Marta ;

Lopez-Rubio, Amparo ;

Lagaron, Jose M. .

JOURNAL OF APPLIED POLYMER SCIENCE, 2013, 128 (05) :2666-2678

[35] Optimization of the nanofabrication by acid hydrolysis of bacterial cellulose nanowhiskers [J].

Martinez-Sanz, Marta ;

Lopez-Rubio, Amparo ;

Lagaron, Jose M. .

CARBOHYDRATE POLYMERS, 2011, 85 (01) :228-236

[36] Development of electrospun EVOH fibres reinforced with bacterial cellulose nanowhiskers. Part I: Characterization and method optimization [J].

Martinez-Sanz, Marta ;

Olsson, Richard T. ;

Lopez-Rubio, Amparo ;

Lagaron, Jose M. .

CELLULOSE, 2011, 18 (02) :335-347

[37] CRYSTALLIZATION AND MELTING BEHAVIOR OF PHB AND PHB/HV COPOLYMER [J].

OWEN, AJ ;

HEINZEL, J ;

SKRBIC, Z ;

DIVJAKOVIC, V .

POLYMER, 1992, 33 (07) :1563-1567

[38] Potential of Ball Milling to Improve Clay Dispersion in Nanocomposites [J].

Perrin-Sarazin, Florence ;

Sepehr, Maryam ;

Bouaricha, Salim ;

Denault, Johanne .

POLYMER ENGINEERING AND SCIENCE, 2009, 49 (04) :651-665

[39] Structure and thermal properties of poly(lactic acid)/cellulose whiskers nanocomposite materials [J].

Petersson, L. ;

Kvien, I. ;

Oksman, K. .

COMPOSITES SCIENCE AND TECHNOLOGY, 2007, 67 (11-12) :2535-2544

[40] Morphology and barrier properties of solvent cast composites of thermoplastic biopolymers and purified cellulose fibers [J].

Sanchez-Garcia, M. D. ;

Gimenez, E. ;

Lagaron, J. M. .

CARBOHYDRATE POLYMERS, 2008, 71 (02) :235-244

← 1 2 3 4 5 6 →