Assessment of Ball Milling as a Compounding Technique to Develop Nanocomposites of Poly(3-Hydroxybutyrate-co-3-Hydroxyvalerate) and Bacterial Cellulose Nanowhiskers

被引：24

作者：

Ambrosio-Martin, Jesus ^{[1
]}

Jose Fabra, Maria ^{[1
]}

Lopez-Rubio, Amparo ^{[1
]}

Gorrasi, Giuliana ^{[2
]}

Sorrentino, Andrea ^{[3
]}

Lagaron, Jose M. ^{[1
]}

机构：

[1] IATA CSIC, Novel Mat & Nanotechnol Grp, Avda Agustin Escardino 7, Valencia 46980, Spain

[2] Univ Salerno, Dept Ind Engn, Via Giovanni Paolo II 132, Salerno, Italy

[3] Natl Res Council CNR, IPCB, Ple Enrico Fermi 1, I-80055 Portici, Italy

来源：

JOURNAL OF POLYMERS AND THE ENVIRONMENT | 2016年 / 24卷 / 03期

关键词：

Polyhydroxyalkanoates; Bacterial cellulose nanowhiskers; Bacterial cellulose nanocrystals; Oxygen barrier; Ball milling; HYDROCHLORIC-ACID HYDROLYSIS; THERMAL-PROPERTIES; CRYSTALLIZATION KINETICS; MELTING BEHAVIOR; CARBON NANOTUBE; PHASE-CHANGE; NANOCRYSTALS; DISPERSION; MORPHOLOGY; BARRIER;

D O I：

10.1007/s10924-016-0767-6

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

The aim of this study was the assessment of high energy ball milling technique to develop poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) nanocomposites containing bacterial cellulose nanowhiskers (BCNW). Crystallization behaviour of PHBV/BCNW nanocomposites was studied under non-isothermal and isothermal conditions using differential scanning calorimetry. The changes in PHBV crystalline structure were also studied using X-ray diffraction. The results confirmed that BCNW acted as nucleating agents and, hence, favored the crystallization of the PHBV. The oxygen permeability of the nanocomposites was reduced by 22 % when compared to that of the neat PHBV. This work provides a new insight into the development of polyhydroxyalkanoate composites by means of the high energy ball milling technique.

引用

页码：241 / 254

页数：14

共 59 条

[1] Melt polycondensation to improve the dispersion of bacterial cellulose into polylactide via melt compounding: enhanced barrier and mechanical properties [J].

Ambrosio-Martin, J. ;

Fabra, M. J. ;

Lopez-Rubio, A. ;

Lagaron, J. M. .

CELLULOSE, 2015, 22 (02) :1201-1226

[2] On the use of ball milling to develop PHBV-graphene nanocomposites (I)-Morphology, thermal properties, and thermal stability [J].

Ambrosio-Martin, Jesus ;

Gorrasi, Giuliana ;

Lopez-Rubio, Amparo ;

Jose Fabra, Maria ;

Cabedo Mas, Luis ;

Angel Lopez-Manchado, Miguel ;

Maria Lagaron, Jose .

JOURNAL OF APPLIED POLYMER SCIENCE, 2015, 132 (24)

[3] Assessment of Ball Milling Methodology to Develop Polylactide-Bacterial Cellulose Nanocrystals Nanocomposites [J].

Ambrosio-Martin, Jesus ;

Lopez-Rubio, Amparo ;

Jose Fabra, Maria ;

Gorrasi, Giuliana ;

Pantani, Roberto ;

Maria Lagaron, Jose .

JOURNAL OF APPLIED POLYMER SCIENCE, 2015, 132 (10)

[4] Enhanced dispersion of cellulose nanocrystals in melt-processed polylactide-based nanocomposites [J].

Arias, Andrea ;

Heuzey, Marie-Claude ;

Huneault, Michel A. ;

Ausias, Gilles ;

Bendahou, Abdelkader .

CELLULOSE, 2015, 22 (01) :483-498

[5] Granulation, Phase Change, and Microstructure - Kinetics of Phase Change. III [J].

Avrami, M .

JOURNAL OF CHEMICAL PHYSICS, 1941, 9 (02) :177-184

[6] Kinetics of phase change I - General theory [J].

Avrami, M .

JOURNAL OF CHEMICAL PHYSICS, 1939, 7 (12) :1103-1112

[7]

Avrami M., 1940, J CHEM PHYS, V8, P212, DOI [10.1063/1.1750631, DOI 10.1063/1.1750631]

[8] Modified layered double hydroxides in polycaprolactone as a tunable delivery system: in vitro release of antimicrobial benzoate derivatives [J].

Bugatti, Valeria ;

Gorrasi, Giuliana ;

Montanari, Francesca ;

Nocchetti, Morena ;

Tammaro, Loredana ;

Vittoria, Vittoria .

APPLIED CLAY SCIENCE, 2011, 52 (1-2) :34-40

[9] Crystallization behavior of poly(hydroxybytyrate-co-valerate) in model and bulk PHBV/kenaf fiber composites [J].

Buzarovska, Aleksandra ;

Bogoeva-Gaceva, Gordana ;

Grozdanov, A. ;

Avella, M. ;

Gentile, G. ;

Errico, M. .

JOURNAL OF MATERIALS SCIENCE, 2007, 42 (16) :6501-6509

[10] A Novel Thermoformable Bionanocomposite Based on Cellulose Nanocrystal-graft-Poly(ε-caprolactone) [J].

Chen, Guangjun ;

Dufresne, Alain ;

Huang, Jin ;

Chang, Peter R. .

MACROMOLECULAR MATERIALS AND ENGINEERING, 2009, 294 (01) :59-67

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