High-nuclear polyoxovanadates assembled from pentagonal building blocks

被引：15
|
作者：
Zhang, Ting [1 ]
Hou, Yuhan [1 ]
Hou, Baoshan [1 ]
Zhao, Liang [1 ]
Wang, Xinlong [1 ,2 ]
Qin, Chao [1 ]
Su, Zhongmin [1 ,2 ]
机构：
[1] Northeast Normal Univ, Key Lab Polyoxometalate & Reticular Mat Chem, Minist Educ, Changchun 130024, Peoples R China
[2] Hainan Univ, Coll Sci, Haikou 570228, Hainan, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2022年 / 58卷 / 79期
关键词：
METAL-ORGANIC POLYHEDRA; OXIDATION; CONSTRUCTION; CATALYST; UNITS; SIZE;
D O I：
10.1039/d2cc04436f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The design and synthesis of high-nuclear polyoxometalates (POMs) constructed from pentagonal molecular building blocks (MBBs) are attractive and challenging. Herein, three new high-nuclear polyoxovanadates, including {V20W2P20} (1), {V18W4P14} (2), and {V26W6P16} (3), have been successfully synthesized under solvothemial conditions. All these structures are assembled from pentagonal MBB {WV5(PhPO3)(5)} with different configurations. Compound 1 exhibits efficient, stable, and versatile catalytic activity for sulfide oxidation.
引用
收藏
页码：11111 / 11114
页数：4
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