β-Octakis(methylthio)porphycenes: synthesis, characterisation and third order nonlinear optical studies

被引：33

作者：

Rana, Anup ^{[1
,2
]}

Lee, Sangsu ^{[3
,4
]}

Kim, Dongho ^{[3
,4
]}

Panda, Pradeepta K. ^{[1
,2
]}

机构：

[1] Univ Hyderabad, Sch Chem, Hyderabad 500046, Andhra Pradesh, India

[2] Univ Hyderabad, Adv Ctr Res High Energy Mat ACRHEM, Hyderabad 500046, Andhra Pradesh, India

[3] Yonsei Univ, Spect Lab Funct Elect Syst, Seoul 120749, South Korea

[4] Yonsei Univ, Dept Chem, Seoul 120749, South Korea

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 36期

基金：

新加坡国家研究基金会;

关键词：

ABSORPTION CROSS-SECTIONS; 2-PHOTON ABSORPTION; PHOTODYNAMIC THERAPY; PORPHYCENE; PORPHYRINS; DERIVATIVES;

D O I：

10.1039/c5cc02279g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel electron deficient beta-octakis(methylthio) porphycene, along with its Zn(II) and Ni(II) derivatives, was synthesized for the first time. The macrocyclic structure exhibits core ruffling with a largely red shifted absorption band (similar to 750 nm) and also a large enhancement in the third order nonlinear optical response.

引用

页码：7705 / 7708

页数：4

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