Conjugated Gold-Porphyrin Monolayers Assembled on Inorganic Surfaces

被引：23

作者：

Contino, Annalinda ^{[1
]}

Maccarrone, Giuseppe ^{[1
]}

Fragala, Maria E. ^{[1
,2
]}

Spitaleri, Luca ^{[1
]}

Gulino, Antonino ^{[1
,2
]}

机构：

[1] Univ Catania, Dept Chem Sci, Viale Andrea Doria 6, I-95125 Catania, Italy

[2] INSTM UdR Catania, Viale Andrea Doria 6, I-95125 Catania, Italy

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2017年 / 23卷 / 59期

关键词：

gold nanoparticles; hybrids; monolayers; nanostructures; porphyrins; ENGINEERED SILICA SURFACE; OPTICAL PH-METER; NANOPARTICLE-SUPERLATTICES; THIN-FILMS; SUPRAMOLECULAR INCORPORATION; CHARGE-TRANSFER; TAILORED HOLES; NANOSTRUCTURES; MOLECULES; LAYER;

D O I：

10.1002/chem.201703523

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Gold nanoparticles show important properties owing to their electronic structures. A limitation of some gold nanoparticles is that they either show surface plasmons or luminescence. The increase in size of the gold nanoparticles, and the appearance of the surface plasmons may result in the disappearance of luminescence. The aim of our study is the nanoscale assembly of Au nanoparticles on a monolayer of porphyrin molecules anchored to functionalized inorganic surfaces. This functional architecture not only exhibits a strong surface plasmon due to the gold nanoparticles, but also a strong luminescence signal from the porphyrin molecules. Finally we observed a long-range order in the Au nanoparticles conjugated to the porphyrin monolayer.

引用

页码：14937 / 14943

页数：7

共 83 条

[1] Size Evaluation of Gold Nanoparticles by UV-vis Spectroscopy [J].

Amendola, Vincenzo ;

Meneghetti, Moreno .

JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (11) :4277-4285

[2]

Auwärter W, 2012, NAT NANOTECHNOL, V7, P41, DOI [10.1038/NNANO.2011.211, 10.1038/nnano.2011.211]

[3] Kinetically Controlled Seeded Growth Synthesis of Citrate-Stabilized Gold Nanoparticles of up to 200 nm: Size Focusing versus Ostwald Ripening [J].

Bastus, Neus G. ;

Comenge, Joan ;

Puntes, Victor .

LANGMUIR, 2011, 27 (17) :11098-11105

[4] Interactions of iodoperfluorobenzene compounds with gold nanoparticles [J].

Blakey, Idriss ;

Merican, Zul ;

Rintoul, Llewellyn ;

Chuang, Ya-Mi ;

Jack, Kevin S. ;

Micallef, Aaron S. .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2012, 14 (10) :3604-3611

[5] Nanocrystallinity and direct cross-linkage as key-factors for the assembly of gold nanoparticle-superlattices [J].

Boterashvili, M. ;

Shirman, T. ;

Popovitz-Biro, R. ;

Wen, Q. ;

Lahav, M. ;

van der Boom, M. E. .

CHEMICAL COMMUNICATIONS, 2016, 52 (52) :8079-8082

[6] Formation of aromatic siloxane self-assembled monolayers [J].

Brandow, Susan L. ;

Chen, Mu-San ;

Dulcey, Charles S. ;

Dressick, Walter J. .

LANGMUIR, 2008, 24 (08) :3888-3896

[7] Designing PbSe nanowires and nanorings through oriented attachment of nanoparticles [J].

Cho, KS ;

Talapin, DV ;

Gaschler, W ;

Murray, CB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (19) :7140-7147

[8] Linear vs Exponential Formation of Molecular-Based Assemblies [J].

Choudhury, Joyanta ;

Kaminker, Revital ;

Motiei, Leila ;

de Ruiter, Graham ;

Morozov, Michael ;

Lupo, Fabio ;

Gulino, Antonino ;

van der Boom, Milko E. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (27) :9295-9297

[9] Long range order in Si(100) surfaces engineered with porphyrin nanostructures [J].

Cristaldi, Domenico A. ;

Motta, Alessandro ;

Millesi, Salvatrice ;

Gupta, Tarkeshwar ;

Chhatwal, Megha ;

Gulino, Antonino .

JOURNAL OF MATERIALS CHEMISTRY C, 2013, 1 (32) :4979-4984

[10] Sensing of linear alkylammonium ions by a 5-pyrenoylamido-calix[5]arene solution and monolayer using luminescence measurements [J].

Cristaldi, Domenico A. ;

Fragala, Ignazio ;

Pappalardo, Andrea ;

Toscano, Rosa M. ;

Ballistreri, Francesco P. ;

Tomaselli, Gaetano A. ;

Gulino, Antonino .

JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (02) :675-683

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