Optically passive counter electrodes for electrochromic devices: transition metal cerium oxide thin films

被引:18
作者
Azens, A
Kullman, L
Ragan, DD
Granqvist, CG
机构
[1] Uppsala Univ, Dept Mat Sci, S-75121 Uppsala, Sweden
[2] Univ Calif Santa Barbara, Dept Mat, Santa Barbara, CA 93106 USA
关键词
electrochromism; W oxide; Ti oxide; Ce oxide; W-Ce oxide; Ti-Ce oxide; optical properties; counter electrode;
D O I
10.1016/S0927-0248(97)00267-5
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Films of W-Ce oxide and Ti-Ce oxide were made by reactive DC magnetron sputtering. Li+ intercalation/deintercalation showed that the electrochromic coloration efficiency depended on the Ce/W and Ce/Ti ratio, and at proper values of these ratios the films remained transparent irrespective of their ion content. Ti-Ce oxide combines this property with good electrochemical cycling durability, and this material can serve as a counter electrode in transparent electrochromic devices. (C) 1997 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:85 / 91
页数:7
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