Coating Formation on Ti-6Al-4V Alloy by Micro Arc Oxidation in Molten Salt

被引:30
作者
Sobolev, Alexander [1 ]
Wolicki, Israel [1 ]
Kossenko, Alexey [1 ]
Zinigrad, Michael [1 ]
Borodianskiy, Konstantin [1 ]
机构
[1] Ariel Univ, Dept Chem Engn Biotechnol & Mat, Zimin Adv Mat Lab, IL-40700 Ariel, Israel
关键词
micro arc oxidation; titanium coating; titanium oxide; molten salt; PLASMA ELECTROLYTIC OXIDATION; 6061; ALUMINUM-ALLOY; MECHANICAL-PROPERTIES; TITANIUM-ALLOY; CORROSION-RESISTANCE; CERAMIC COATINGS; PEO COATINGS; BEHAVIOR; GROWTH; TI;
D O I
10.3390/ma11091611
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Micro Arc Oxidation (MAO) is an electrochemical surface treatment process to produce oxide protective coatings on some metals. MAO is usually conducted in an aqueous electrolyte, which requires an intensive bath cooling and leads to the formation of a coating containing impurities that originate in the electrolyte. In the current work, we applied an alternative ceramic coating to the Ti-6Al-4V alloy using the MAO process in molten nitrate salt at a temperature of 280 degrees C. The obtained coating morphology, chemical and phase composition, and corrosion resistance were investigated and described. The obtained results showed that a coating of 2.5 mu m was formed after 10 min of treatment, containing titanium oxide and titaniumaluminum intermetallic phases. Morphological examination indicated that the coating is free of cracks and contains round, homogeneously distributed pores. Corrosion resistance testing indicated that the protective oxide coating on Ti alloy is 20 times more resistive than the untreated alloy.
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页数:8
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