Reduction of phosphine oxides to phosphines with the InBr3/TMDS system

被引：45

作者：

Pehlivan, Leyla ^{[1
]}

Metay, Estelle ^{[1
]}

Delbrayelle, Dominique ^{[2
]}

Mignani, Gerard ^{[3
]}

Lemaire, Marc ^{[1
]}

机构：

[1] Univ Lyon 1, CNRS UMR5246, ICBMS, Lab Catalyse & Synth Organ, F-69622 Villeurbanne, France

[2] Minakem SAS, F-59310 Beuvry La Foret, France

[3] Lyon Res Ctr, Rhodia, F-69192 St Fons, France

来源：

TETRAHEDRON | 2012年 / 68卷 / 15期

关键词：

Reduction; Phosphine oxide; TMDS; InBr3; Phosphine; CATALYTIC-SYSTEM; DEOXYGENATION; ETHERS; ESTERS; MECHANISM; SECONDARY; ALCOHOLS; HALIDES; AMINES; ALANE;

D O I：

10.1016/j.tet.2012.02.063

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient method for the reduction of phosphine oxide derivatives into their corresponding phosphines is described. The system InBr3/TMDS allows the reduction of different secondary and tertiary phosphine oxides as well as aliphatic and aromatic phosphine oxides. (C) 2012 Elsevier Ltd. All rights reserved.

引用

页码：3151 / 3155

页数：5

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