Tetraaquabis[4-(4H-1,2,4-triazol-4-yl)benzoato-κN1]nickel(II) decahydrate

被引：0
|
作者：
Sun, Weixuan [2 ]
Yu, Yaqin [2 ]
Wang, Guanjun [1 ]
Wu, Xiaohui
机构：
[1] Jilin Univ, Dept Hematol, Hosp 1, Changchun 130021, Peoples R China
[2] Jilin Univ, Sch Publ Hlth, Dept Prevent Med, Changchun 130021, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2012年 / 68卷
关键词：
Data-to-parameter ratio = 12.9; Mean σ(C-C) = 0.005 Å; R factor = 0.049; Single-crystal X-ray study; T = 293 K; wR factor = 0.119;
D O I：
10.1107/S1600536811051063
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title compound, [Ni(C9H6N3O2)(2)(H2O)(4)]center dot 10H(2)O, the Ni-II ion lies on a twofold rotation axis and displays a slightly distorted octahedral geometry defined by two N atoms from two monodentate 4-(1,2,4-triazol-4-yl) benzoate ligands and four water molecules, two of which also lie on the twofold rotation axis. In the crystal, the complex molecules and uncoordinated water molecules are linked via intermolecular O-H center dot center dot center dot N and O-H center dot center dot center dot O hydrogen bonds, forming a three-dimensional supramolecular network. pi-pi interactions between the benzene rings provide additional stability of the crystal packing [centroid-centroid distance = 3.792 (2) angstrom].
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页码：M10 / +
页数：10
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