Radical-ligand-derived C-N coupling, Ga(III)-radical vs low-spin Co(III)-radical reactivity

被引：23

作者：

Chaudhuri, Phalguni ^{[1
]}

Bill, Eckhard ^{[1
]}

Wagner, Rita ^{[1
]}

Pieper, Ulrich ^{[1
]}

Biswas, Biplab ^{[1
]}

Weyhermueller, Thomas ^{[1
]}

机构：

[1] Max Planck Inst Bioanorgan Chem, Mulheim, Germany

来源：

INORGANIC CHEMISTRY | 2008年 / 47卷 / 13期

关键词：

D O I：

10.1021/ic8006348

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The redox-active ligand 2-(3,5-dimethoxyanilino)-4,6-di-tert-butylphenol, H2LOCH3, results in, as expected, a trisradical complex with a low-spin Co(III) center, [Co-III(L-OCH3 center dot)(3)] (1), whereas the Ga(III) center yields a coordinated new hexadentate monoradical ligand, [(GaL1 center dot)-L-III] (2), presumably due to the ligand-derived redox activity involving C-H activation.

引用

页码：5549 / 5551

页数：3

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