Scientific foundations and effective chemical methods of combustion, explosion, and gas detonation control

被引：25

作者：

Azatyan, V. V. ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Struct Macrokinet & Mat Sci, Chernogolovka 142432, Moscow Oblast, Russia

来源：

RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A | 2011年 / 85卷 / 08期

基金：

俄罗斯基础研究基金会;

关键词：

combustion; chemical methods; explosion; gas detonation; self-heating; chain reaction; HYDROGEN-AIR MIXTURES; INHIBITION; IGNITION; MECHANISM; OXYGEN; LIMIT;

D O I：

10.1134/S0036024411080036

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The competition between the branching and termination of reaction chains is shown to determine all general laws of gas combustion and explosion not only at pressures much lower that atmospheric, but also at atmospheric and increased pressures upon self-heating. It is established that the role of any elementary reaction in combustion is determined primarily by its effect on the relation between the rates of chain branching and termination. Scientific foundations and effective chemical methods of combustion, explosion, and combustible gas detonation control are developed.

引用

页码：1293 / 1306

页数：14