Pre-treatment with nanofiltration (NF) in seawater desalination-Preliminary integrated membrane tests in Urla, Turkey

被引:80
作者
Kaya, Cuneyt [1 ]
Sert, Gokhan [2 ]
Kabay, Nalan [3 ]
Arda, Muserref [1 ]
Yuksel, Mithat [3 ]
Egemen, Ozdemir [2 ]
机构
[1] Ege Univ, Fac Sci, Dept Chem, Izmir, Turkey
[2] Ege Univ, Fac Fisheries, Izmir, Turkey
[3] Ege Univ, Fac Engn, Dept Chem Engn, Izmir, Turkey
关键词
Desalination; Integrated system; Reverse osmosis; Nanofiltration; Seawater; REVERSE-OSMOSIS; PILOT-PLANT; RECOVERY; SYSTEM; WATER;
D O I
10.1016/j.desal.2015.04.029
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
In this study, the applicability of nanofiltration (NF) was investigated as a pre-treatment stage of reverse osmosis (RU) process for seawater desalination. The desalination performance of such integrated system was checked. Previously, NF (NF90 and NF270) and SWRO (SW30) membranes were used individually in the close-loop operation. Next, the NF permeate was collected using NF membrane by a continuous operation and then this permeate was used as a feed for a closed-loop SWRO system. The performances of single SWRO, NF and NF + RO integrated systems were compared in terms of permeate qualities and quantities. The results showed that permeate recovery of NF270 membrane was higher than that of NF90 membrane. However, the salt rejection of NF90 membrane was better than that of NF270. The single SW3O-RO membrane showed an average rejection of 98.2% for salinity, while the permeate recovery value was only 28% at 55 bar. Also the average permeate flux of single SW3O-RO membrane was 30.1 L/h m(2). For the integrated system experiments, the highest permeate flux was found with NF90 (30 bar) + SW3O-RO (40 bar) combination. Similar permeate flux values were obtained with single 5W30-RO and NF90 (30 bar) + SW3O-RO (30) bar combination. The lowest permeate flux was found with NF270 (30 bar) + SW3O-RO (40 bar) combination. Salinity was also highly rejected by all integrated system combinations. Permeate recovery values of integrated system combinations showed similar trend with permeate flux. Regarding permeate quality, it was seen that all integrated system combinations were better than single SW3O-RO membrane. It was obtained that the permeate quality with NF90 + SW3O-RO combination was better than that with NF270 + SW3O-RO combination. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码:10 / 17
页数:8
相关论文
共 20 条
[1]   The role of membrane surface charge and solute physico-chemical properties in the rejection of organic acids by NF membranes [J].
Bellona, C ;
Drewes, JE .
JOURNAL OF MEMBRANE SCIENCE, 2005, 249 (1-2) :227-234
[2]   Performance evaluation of three different pretreatment systems for seawater reverse osmosis technique [J].
BouHamad, S ;
AbdelJawad, M ;
Ebrahim, S ;
AlMansour, M ;
AlHijji, A .
DESALINATION, 1997, 110 (1-2) :85-91
[3]   Submerged hollow fiber ultrafiltration as seawater pretreatment in the logic of integrated membrane desalination systems [J].
Di Profio, Gianluca ;
Ji, Xiaoshen ;
Curcio, Efrem ;
Drioli, Enrico .
DESALINATION, 2011, 269 (1-3) :128-135
[4]   Integrated system for recovery of CaCO3, NaCl and MgSO4.7H2O from nanofiltration retentate [J].
Drioli, E ;
Curcio, E ;
Criscuoli, A ;
Di Profio, G .
JOURNAL OF MEMBRANE SCIENCE, 2004, 239 (01) :27-38
[5]   Integrated membrane operations for seawater desalination [J].
Drioli, E ;
Criscuoli, A ;
Curcio, E .
DESALINATION, 2002, 147 (1-3) :77-81
[6]   Reverse osmosis desalination: Water sources, technology, and today's challenges [J].
Greenlee, Lauren F. ;
Lawler, Desmond F. ;
Freeman, Benny D. ;
Marrot, Benoit ;
Moulin, Philippe .
WATER RESEARCH, 2009, 43 (09) :2317-2348
[7]   Impact of desalination plants fluid effluents on the integrity of seawater, with the Arabian Gulf in perspective [J].
Hashim, A ;
Hajjaj, M .
DESALINATION, 2005, 182 (1-3) :373-393
[8]   A new approach to membrane and thermal seawater desalination processes using nanofiltration membranes (Part 1) [J].
Hassan, AM ;
Al-Sofi, MAK ;
Al-Amoudi, AS ;
Jamaluddin, ATM ;
Farooque, AM ;
Rowaili, A ;
Dalvi, AGI ;
Kither, NM ;
Mustafa, GM ;
Al-Tisan, IAR .
DESALINATION, 1998, 118 (1-3) :35-51
[9]   Nanofiltration of highly concentrated salt solutions up to seawater salinity [J].
Hilal, N ;
Al-Zoubi, H ;
Mohammad, AW ;
Darwish, NA .
DESALINATION, 2005, 184 (1-3) :315-326
[10]   A comprehensive review of nanofiltration membranes: Treatment, pretreatment, modelling, and atomic force microscopy [J].
Hilal, N ;
Al-Zoubi, H ;
Darwish, NA ;
Mohammad, AW ;
Abu Arabi, M .
DESALINATION, 2004, 170 (03) :281-308