Aqueous organometallic chemistry with nitrogen ligands: Synthesis of hydrophilic platinum(0) olefin complexes

被引：36

作者：

Kundu, A ^{[1
]}

Buffin, BP ^{[1
]}

机构：

[1] Western Michigan Univ, Dept Chem, Kalamazoo, MI 49008 USA

来源：

ORGANOMETALLICS | 2001年 / 20卷 / 17期

关键词：

D O I：

10.1021/om010212k

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions of hydrophilic unsymmetrical pyridine-imine chelating ligands with pt(eta (2)-norbornene)(3) in the presence of olefins that contain electron-withdrawing substituents afford water-soluble three-coordinate Pt-(0) complexes. The stability of these organometallic complexes in aqueous solution is dependent on the position of the hydrophilic charged substituents in the chelating ligand and the electronic nature of the coordinated olefin.

引用

页码：3635 / 3637

页数：3

共 35 条

[1] Cationic unsymmetrical 1,4-diazabutadiene complexes of platinum(II) [J].

Albietz, PJ ;

Yang, KY ;

Lachicotte, RJ ;

Eisenberg, R .

ORGANOMETALLICS, 2000, 19 (18) :3543-3555

[2]

Anastas P. T., 1998, GREEN CHEM FRONTIERS

[3] The role of catalysis in the design, development, and implementation of green chemistry [J].

Anastas, PT ;

Bartlett, LB ;

Kirchhoff, MM ;

Williamson, TC .

CATALYSIS TODAY, 2000, 55 (1-2) :11-22

[4] Striving for catalytically green processes in the 21st century [J].

Armor, JN .

APPLIED CATALYSIS A-GENERAL, 1999, 189 (02) :153-162

[5] A novel palladium catalyst for the synthesis of hydrogen peroxide from carbon monoxide, water and oxygen [J].

Bianchi, D ;

Bortolo, R ;

D'Aloisio, R ;

Ricci, M .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1999, 150 (1-2) :87-94

[6] [Pd0(N,N-chelate)(olefin)] complexes containing nitrogen chelates derived from carbohydrates and their use in mild hydrogenation of olefins in water [J].

Borriello, C ;

Ferrara, ML ;

Orabona, I ;

Panunzi, A ;

Ruffo, F .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (15) :2545-2550

[7] Production of hydrogen peroxide from oxygen and alcohols, catalyzed by palladium complexes [J].

Bortolo, R ;

Bianchi, D ;

D'Aloisio, R ;

Querci, C ;

Ricci, M .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2000, 153 (1-2) :25-29

[8]

BUFFIN BP, UNPUB

[9] Synthesis, characterization and X-ray structural determination of palladium(0)-olefin complexes containing pyridin-thioethers as ancillary ligands. Equilibria and rates of olefin and ligand exchange [J].

Canovese, L ;

Visentin, F ;

Chessa, G ;

Uguagliati, P ;

Dolmella, A .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2000, 601 (01) :1-15

[10]

CORNILS B, 1995, CHEMTECH, V25, P33

← 1 2 3 4 →