Topological variability of Zn(II) and Co(II) 3D coordination polymers obtained through solvothermal in situ disulfide cleavage

被引：20

作者：

Bu, Yang ^{[1
,2
]}

Jiang, Feilong ^{[1
]}

Zhang, Shuquan ^{[1
,2
]}

Ma, Jie ^{[1
,2
]}

Li, Xingjun ^{[1
,2
]}

Hong, Maochun ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

[2] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China

来源：

CRYSTENGCOMM | 2011年 / 13卷 / 21期

关键词：

METAL-ORGANIC FRAMEWORKS; LIGAND SYNTHESIS; S-S; ROTATION; CRYSTAL; BONDS;

D O I：

10.1039/c1ce05592e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two three-dimensional coordination polymers were solvothermally prepared through in situ formation of a 2-sulfobenzoic acid ligand from a 2,2'-dithiobisbenzoic acid precursor involving the oxidative cleavage of its disulfide bond. Complex 1 shows neb-e topology, while complex 2 exhibits a scarcely reported twisting chiral dense 7(5).9 net.

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收藏

页码：6323 / 6326

页数：4

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