Behavior of Na and K in the extraction process of lithium isotope separation

被引：5

作者：

Kostikova, G. V. ^{[1
]}

Maltseva, I. E. ^{[1
]}

Krasnova, O. G. ^{[1
]}

Shokurova, N. A. ^{[1
]}

Zhilov, V. I. ^{[1
]}

机构：

[1] Russian Acad Sci, AN Frumkin Inst Phys Chem & Electrochem, Bldg 4,31 Leninsky Prosp, Moscow 119071, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2018年 / 67卷 / 12期

基金：

俄罗斯科学基金会;

关键词：

extraction; lithium; sodium; potassium; benzo-15-crown-5; LIQUID-LIQUID-EXTRACTION; BENZO-15-CROWN-5;

D O I：

10.1007/s11172-018-2353-7

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The extraction behavior of Na and K during lithium isotope separation using benzo-15-crown-5 (B15C5) in chloroform as the extractant was investigated. It was found that potassium was extracted better than sodium and lithium, the metal: B15C5 ratio in the extracted compound was 1: 1 for all metals. It was shown that in the extraction systems with a LiCl concentration higher than 5 mol L-1, B15C5 was noticeably transferred into aqueous solutions, while concentrated LiCl solutions had a salting-out effect with respect to Na and K.

引用

页码：2188 / 2190

页数：3

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