Enantioselective synthesis of metathesis-derived ureapeptoid macrocycles

被引：6

作者：

Wang, XZ ^{[1
]}

Burke, TR ^{[1
]}

机构：

[1] NCI, Med Chem Lab, Ctr Canc Res, NIH, Frederick, MD 21701 USA

来源：

SYNLETT | 2004年 / 03期

关键词：

asymmetric synthesis; macrocycles; metathesis; ring closure; stereoselective;

D O I：

10.1055/s-2004-815425

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Ring-closing metathesis (RCM) was used for the preparation of the first member of a new class of ureapeptoid-containing macrocycles. Key to the approach was the enantioselective synthesis of functionalized carbamoyl alkenylglycine equivalents using (-)-B-allyldiisopinocampheylborane [(-)-d-Ipc(2)Ball]-mediated asymmetric allylation.

引用

页码：469 / 472

页数：4

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