Self-Assembly of a Metal-Organic Framework by Stepwise Coordination of Carboxyl and Pyrrolyl Groups

被引：7

作者：

Xue, Qiang ^{[1
]}

Xue, Na ^{[3
]}

Li, Jie ^{[3
]}

Li, Yaru ^{[3
]}

Li, Ruoning ^{[1
]}

Zhang, Yajie ^{[1
]}

Li, Na ^{[1
]}

Shen, Ziyong ^{[1
]}

Hou, Shimin ^{[1
]}

Wang, Yongfeng ^{[1
,2
]}

机构：

[1] Peking Univ, Dept Elect, Key Lab Phys & Chem Nanodevices, Beijing 100871, Peoples R China

[2] Beijing Acad Quantum Informat Sci, Beijing 100193, Peoples R China

[3] Peking Univ, Informat Technol Inst Tianjin Binhai, Tianjin 300450, Peoples R China

来源：

JOURNAL OF PHYSICAL CHEMISTRY C | 2020年 / 124卷 / 14期

基金：

中国国家自然科学基金;

关键词：

SUPRAMOLECULAR SYSTEMS; NETWORKS; POLYMERIZATION;

D O I：

10.1021/acs.jpcc.9b11599

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The coordination abilities of different functional groups play fundamental roles in metal-organic frameworks. The coordination of indole-4-carboxylic acid with Fe on surfaces was investigated by scanning tunneling microscopy and density functional theory. The carboxyl group reacted with Fe atoms to form tetramers in a deprotonation process on Au(111) at room temperature. The deprotonation of pyrrolyl groups occurred at around 350 K, forming coordinated tetramer chains and rotiform structures. The arrangement of tetrameric clusters and coordination chains on Au(100) was influenced by surface reconstitution. A two-dimensional coordination network was obtained on Ag(111) without the influence of surface reconstitution.

引用

页码：7790 / 7796

页数：7

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