Growth of graphene on Cu by plasma enhanced chemical vapor deposition

被引:166
作者
Terasawa, Tomo-o
Saiki, Koichiro [1 ,2 ]
机构
[1] Univ Tokyo, Dept Complex Sci & Engn, Chiba 2778561, Japan
[2] Univ Tokyo, Dept Complex Sci & Engn, Chiba 2778561, Japan
关键词
LARGE-AREA; FILMS; GRAPHITE; HYDROGEN;
D O I
10.1016/j.carbon.2011.09.047
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The growth of graphene on Cu substrates by plasma enhanced chemical vapor deposition (PE-CVD) was investigated and its growth mechanism was discussed. At a substrate temperature of 500 degrees C, formation of graphene was found to precede the growth of carbon nanowalls (CNWs), which are often fabricated by PE-CVD. The growth of graphene was investigated in various conditions, changing the plasma power, gas pressures, and the substrate temperature. The catalytic nature of Cu also affects the growth of monolayer graphene at high substrate temperatures, while the growth at low temperatures and growth of multilayer graphene are dominated mostly by radicals generated in the plasma. (C) 2011 Elsevier Ltd. All rights reserved.
引用
收藏
页码:869 / 874
页数:6
相关论文
共 29 条
[1]   Electronic confinement and coherence in patterned epitaxial graphene [J].
Berger, Claire ;
Song, Zhimin ;
Li, Xuebin ;
Wu, Xiaosong ;
Brown, Nate ;
Naud, Cecile ;
Mayou, Didier ;
Li, Tianbo ;
Hass, Joanna ;
Marchenkov, Atexei N. ;
Conrad, Edward H. ;
First, Phillip N. ;
de Heer, Wait A. .
SCIENCE, 2006, 312 (5777) :1191-1196
[2]   Role of Kinetic Factors in Chemical Vapor Deposition Synthesis of Uniform Large Area Graphene Using Copper Catalyst [J].
Bhaviripudi, Sreekar ;
Jia, Xiaoting ;
Dresselhaus, Mildred S. ;
Kong, Jing .
NANO LETTERS, 2010, 10 (10) :4128-4133
[3]   General equation for the determination of the crystallite size La of nanographite by Raman spectroscopy [J].
Cançado, LG ;
Takai, K ;
Enoki, T ;
Endo, M ;
Kim, YA ;
Mizusaki, H ;
Jorio, A ;
Coelho, LN ;
Magalhaes-Paniago, R ;
Pimenta, MA .
APPLIED PHYSICS LETTERS, 2006, 88 (16)
[4]   Intrinsic and extrinsic performance limits of graphene devices on SiO2 [J].
Chen, Jian-Hao ;
Jang, Chaun ;
Xiao, Shudong ;
Ishigami, Masa ;
Fuhrer, Michael S. .
NATURE NANOTECHNOLOGY, 2008, 3 (04) :206-209
[5]   Large-area ultrathin films of reduced graphene oxide as a transparent and flexible electronic material [J].
Eda, Goki ;
Fanchini, Giovanni ;
Chhowalla, Manish .
NATURE NANOTECHNOLOGY, 2008, 3 (05) :270-274
[6]   Raman spectroscopy of graphene and graphite: Disorder, electron-phonon coupling, doping and nonadiabatic effects [J].
Ferrari, Andrea C. .
SOLID STATE COMMUNICATIONS, 2007, 143 (1-2) :47-57
[7]   Epitaxial Graphene on Cu(111) [J].
Gao, Li ;
Guest, Jeffrey R. ;
Guisinger, Nathan P. .
NANO LETTERS, 2010, 10 (09) :3512-3516
[8]   The rise of graphene [J].
Geim, A. K. ;
Novoselov, K. S. .
NATURE MATERIALS, 2007, 6 (03) :183-191
[9]   Doping graphene with metal contacts [J].
Giovannetti, G. ;
Khomyakov, P. A. ;
Brocks, G. ;
Karpan, V. M. ;
van den Brink, J. ;
Kelly, P. J. .
PHYSICAL REVIEW LETTERS, 2008, 101 (02)
[10]   Fabrication of vertically aligned carbon nanowalls using capacitively coupled plasma-enhanced chemical vapor deposition assisted by hydrogen radical injection [J].
Hiramatsu, M ;
Shiji, K ;
Amano, H ;
Hori, M .
APPLIED PHYSICS LETTERS, 2004, 84 (23) :4708-4710