Crystal structure of new rare-earth boron-rich solids:: REB28.5C4

被引：10

作者：

Zhang, FX ^{[1
]}

Xu, FF ^{[1
]}

Mori, T ^{[1
]}

Liu, QL ^{[1
]}

Sato, A ^{[1
]}

Tanaka, T ^{[1
]}

机构：

[1] Natl Inst Mat Sci, Adv Mat Lab, Tsukuba, Ibaraki 3050044, Japan

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 2001年 / 329卷 / 1-2期

关键词：

rare earth compounds; crystal growth; crystal structure; X-ray diffraction; TEM;

D O I：

10.1016/S0925-8388(01)01581-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

New rare-earth boron-rich solids of the composition REB28.5C4 (Re = Y, Ho, Er, Tm and Lu) were synthesized by solid state reaction and single crystals were grown using a high temperature metal solution method. The structure was solved by a direct method from single crystal X-ray diffraction data with Y-B-C as a representative. It shows a layered structure with trigonal symmetry (space group: R (3) over barm (No. 166)) and the unit cell parameters are: a = b = 5.6457(9) Angstrom, c = 56.8873(13) Angstrom. (C) 2001 Elsevier Science B.V. All tights reserved.

引用

页码：168 / 172

页数：5

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