Surface tension of electrolytes:: Specific ion effects explained by dispersion forces

被引：276
|
作者：
Boström, M [1 ]
Williams, DRM [1 ]
Ninham, BW [1 ]
机构：
[1] Australian Natl Univ, Inst Adv Studies, Res Sch Phys Sci & Engn, Dept Appl Math, Canberra, ACT 0200, Australia
来源：
LANGMUIR | 2001年 / 17卷 / 15期
关键词：
D O I：
10.1021/la0102298
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The surface tension of ionic solutions shows marked specific ion effects not explained by existing theories. The effects are here accounted for by invoking a dispersion force between ions and the air-water interface. The measurements can be explained with reasonable values for the dispersion potential.
引用
收藏
页码：4475 / 4478
页数：4
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