Porphyrin-containing D-π-A conjugated polymer with absorption over the entire spectrum of visible light and its applications in solar cells

被引：32
作者：
Shi, Shaowei [1 ]
Wang, Xiaochen [1 ]
Sun, Yeping [1 ,2 ]
Chen, Song [3 ]
Li, Xiaoyu [1 ]
Li, Yongfang [2 ]
Wang, Haiqiao [1 ]
机构：
[1] Beijing Univ Chem Technol, State Key Lab Organ Inorgan Composite, Key Lab Carbon Fiber & Funct Polymers, Minist Educ, Beijing 100029, Peoples R China
[2] Chinese Acad Sci, Inst Chem, CAS Key Lab Organ Solids, Beijing 100190, Peoples R China
[3] China Text Acad, Beijing 100025, Peoples R China
来源：
JOURNAL OF MATERIALS CHEMISTRY | 2012年 / 22卷 / 22期
基金：
北京市自然科学基金;
关键词：
PHOTOVOLTAIC PROPERTIES; ORGANIC PHOTOVOLTAICS; FULLERENE; ACCEPTOR; UNITS; COPOLYMERS; DESIGN; DONOR;
D O I：
10.1039/c2jm31649h
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
In this communication, we present the first example of a donor-acceptor porphyrin-containing conjugated copolymer, PCTTQP, with absorption over the entire spectrum of visible light. The BHJ solar cells based on PCTTQP : PC71BM blends displayed a PCE of 2.5%, which is the highest value in porphyrin-based conjugated polymers.
引用
收藏
页码：11006 / 11008
页数：3
相关论文
共 29 条
  • [1] Akita M., 2012, ANGEW CHEM INT EDIT, V51, P1
  • [2] Building molecular wires from the colours of life: conjugated porphyrin oligomers
    Anderson, HL
    [J]. CHEMICAL COMMUNICATIONS, 1999, (23) : 2323 - 2330
  • [3] Tailoring porphyrins and chlorins for self-assembly in biomimetic artificial antenna systems
    Balaban, TS
    [J]. ACCOUNTS OF CHEMICAL RESEARCH, 2005, 38 (08) : 612 - 623
  • [4] Toward a rational design of poly(2,7-carbazole) derivatives for solar cells
    Blouin, Nicolas
    Michaud, Alexandre
    Gendron, David
    Wakim, Salem
    Blair, Emily
    Neagu-Plesu, Rodica
    Belletete, Michel
    Durocher, Gilles
    Tao, Ye
    Leclerc, Mario
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (02) : 732 - 742
  • [5] Polymer-Fullerene Bulk-Heterojunction Solar Cells
    Brabec, Christoph J.
    Gowrisanker, Srinivas
    Halls, Jonathan J. M.
    Laird, Darin
    Jia, Shijun
    Williams, Shawn P.
    [J]. ADVANCED MATERIALS, 2010, 22 (34) : 3839 - 3856
  • [6] Synthesis of Conjugated Polymers for Organic Solar Cell Applications
    Cheng, Yen-Ju
    Yang, Sheng-Hsiung
    Hsu, Chain-Shu
    [J]. CHEMICAL REVIEWS, 2009, 109 (11) : 5868 - 5923
  • [7] Polymer-Fullerene Bulk-Heterojunction Solar Cells
    Dennler, Gilles
    Scharber, Markus C.
    Brabec, Christoph J.
    [J]. ADVANCED MATERIALS, 2009, 21 (13) : 1323 - 1338
  • [8] Porphyrin-dithienothiophene π-conjugated copolymers:: Synthesis and their applications in field-effect transistors and solar cells
    Huang, Xuebin
    Zhu, Chunli
    Zhang, Shiming
    Li, Weiwei
    Guo, Yunlong
    Zhan, Xiaowei
    Liu, Yunqi
    Bo, Zhishan
    [J]. MACROMOLECULES, 2008, 41 (19) : 6895 - 6902
  • [9] Giant multiporphyrin arrays as artificial light-harvesting antennas
    Imahori, H
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (20) : 6130 - 6143
  • [10] Porphyrin-diones and porphyrin-tetraones: Reversible redox units being localized within the porphyrin macrocycle and their effect on tautomerism
    Kadish, Karl M.
    E, Wenbo
    Zhan, Riqiang
    Khoury, Tony
    Govenlock, Linda J.
    Prashar, Jognandan K.
    Sintic, Paul J.
    Ohkubo, Kei
    Fukuzumi, Shunichi
    Crossley, Maxwell J.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (20) : 6576 - 6588
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