Metal-semiconductor transition in SmxMn1-xS solid solutions

被引:10
作者
Aplesnin, Sergey [1 ,2 ]
Romanova, Oxana [1 ,2 ]
Har'kov, Anton [1 ,2 ]
Balaev, Dmitrii [1 ]
Gorev, Michail [1 ]
Vorotinov, Alexander [1 ]
Sokolov, Vladimir [3 ]
Pichugin, Andrey [3 ]
机构
[1] Russian Acad Sci, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
[2] Siberian State Aerosp Univ, Krasnoyarsk 660014, Russia
[3] Russian Acad Sci, Inst Inorgan Chem, Siberian Branch, Novosibirsk 630090, Russia
来源
PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS | 2012年 / 249卷 / 04期
基金
俄罗斯基础研究基金会;
关键词
Kondo effect; metal-semiconductor transition; semiconductors; variable-valence elements; MAGNETIC-PROPERTIES; PHASE-TRANSITION; VALENCE; PRESSURE;
D O I
10.1002/pssb.201147327
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
The electrical resistivity of the SmxMn1-xS (0.15=x=0.25) solid solutions in the temperature range of 80-300?K was measured. Minimum and maximum in the temperature dependence of the resistivity were found, respectively, at T=220K for x=0.15 and at T=100K for x=0.2 compounds. This behavior is explained from the result of the mobility-edge movement, the disorder being due to elastic deformation and spin density fluctuations with short-range order. Metalsemiconductor phase transition versus concentration at xc=0.25 is observed. Resistivity is described by scattering electrons with acoustic phonon mode and with localized manganese spin. From the thermal expansion coefficient the compression of the lattice below the Neel temperature for Sm0.2Mn0.8S is found.
引用
收藏
页码:812 / 817
页数:6
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