Synthesis, crystal structure and magnetic property of a Ni(II) complex with 4′-(4-methoxyphenyl)-2,2′:6′,2"-terpyridine

被引：3

作者：

Fu, Wei-Wei ^{[1
]}

Shen, Jing-Run ^{[1
]}

Tang, Zi-Qing ^{[1
]}

Peng, Yong-Qiong ^{[1
]}

Yi, Qing ^{[1
]}

机构：

[1] Hengyang Normal Univ, Coll Chem & Mat Sci, Hunan Prov Coll, Key Lab Funct Organometall Mat, Hengyang 421008, Hunan, Peoples R China

来源：

INORGANIC AND NANO-METAL CHEMISTRY | 2017年 / 47卷 / 12期

关键词：

Nickel complex; Crystal structure; Magnetic property; Terpyridine; COORDINATION POLYMERS; METAL; LIGAND; DERIVATIVES; REDOX; IONS; ACID;

D O I：

10.1080/24701556.2017.1357596

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A complex [Ni(meophtpy)(2)](ClO4)(2)center dot 2H(2)O (1) (meophtpy = 4'-(4-methoxyphenyl)-2,2':6',2 ''-terpyridine) has been synthesized and characterized by IR, element analysis, TGA and single crystal X-ray diffraction. The complex crystallizes in Tetragonal system with space group I4(1)/a, a = 24.470(4), b = 24.470(4), c = 13.845(5)angstrom, V = 8290.12 angstrom(3), Dc = 1.558 g/cm(3), Z = 8, F(000) = 4016, final GOF = 1.021, R-1 = 0.0619, and wR(2) = 0.1261 for 3616 observed reflections with I > 2 sigma(I). The crystal structure analysis shows that a three dimensional network overlapped with terpyridine motifs was formed by hydrogen bonds and pi-pi interactions which are seldom found in terpyridine complexes. Themagnetic property of 1 has also been investigated.

引用

页码：1664 / 1667

页数：4

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