Perylene Anhydride Fused Porphyrins as Near-Infrared Sensitizers for Dye-Sensitized Solar Cells

被引：117

作者：

Jiao, Chongjun ^{[2
]}

Zu, Ningning ^{[1
]}

Huang, Kuo-Wei ^{[3
,4
]}

Wang, Peng ^{[1
]}

Wu, Jishan ^{[2
,5
]}

机构：

[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China

[2] Natl Univ Singapore, Dept Chem, Singapore 117543, Singapore

[3] KAUST, Catalysis Ctr, Thuwal 239556900, Saudi Arabia

[4] KAUST, Div Chem & Life Sci & Engn, Thuwal 239556900, Saudi Arabia

[5] ASTAR, Inst Mat Res & Engn, Singapore 117602, Singapore

来源：

ORGANIC LETTERS | 2011年 / 13卷 / 14期

关键词：

IR ABSORPTION; TAPES;

D O I：

10.1021/ol201303h

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Two perylene anhydride fused porphyrins 1 and 2 have been synthesized and employed successfully in dye-sensitized solar cells (DSCs). Both compounds showed broad incident monochromatic photon-to-current conversion efficiency spectra covering the entire visible spectral region and even extending into the near-Infrared (NIR) region up to 1000 nm, which is impressive for ruthenium-tree dyes in DSCs.

引用

页码：3652 / 3655

页数：4

共 37 条

[1] Synthesis of perylene-3,4-mono(dicarboximide)-fullerene C60 dyads as new light-harvesting systems [J].

Baffreau, Jerome ;

Ordronneau, Lucie ;

Leroy-Lhez, Stephanie ;

Hudhomme, Pietrick .

JOURNAL OF ORGANIC CHEMISTRY, 2008, 73 (16) :6142-6147

[2] Highly Efficient Mesoscopic Dye-Sensitized Solar Cells Based on Donor-Acceptor-Substituted Porphyrins [J].

Bessho, Takeru ;

Zakeeruddin, Shaik M. ;

Yeh, Chen-Yu ;

Diau, Eric Wei-Guang ;

Graetzel, Michael .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (37) :6646-6649

[3] Ultrafast electron injection: Implications for a photoelectrochemical cell utilizing an anthocyanin dye-sensitized TiO2 nanocrystalline electrode [J].

Cherepy, NJ ;

Smestad, GP ;

Gratzel, M ;

Zhang, JZ .

JOURNAL OF PHYSICAL CHEMISTRY B, 1997, 101 (45) :9342-9351

[4] A Porphyrin Fused to Four Anthracenes [J].

Davis, Nicola K. S. ;

Thompson, Amber L. ;

Anderson, Harry L. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (01) :30-31

[5] Bis-Anthracene Fused Porphyrins: Synthesis, Crystal Structure, and Near-IR Absorption [J].

Davis, Nicola K. S. ;

Thompson, Amber L. ;

Anderson, Harry L. .

ORGANIC LETTERS, 2010, 12 (09) :2124-2127

[6] Fused Pyrene-Diporphyrins: Shifting Near-Infrared Absorption to 1.5 μm and Beyond [J].

Diev, Vyacheslav V. ;

Hanson, Kenneth ;

Zimmerman, Jeramy D. ;

Forrest, Stephen R. ;

Thompson, Mark E. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (32) :5523-5526

[7] Intramolecular charge-transfer tuning of perylenes:: Spectroscopic features and performance in Dye-sensitized solar cells [J].

Edvinsson, Tomas ;

Li, Chen ;

Pschirer, Neil ;

Schoeneboom, Jan ;

Eickemeyer, Felix ;

Sens, Ruediger ;

Boschloo, Gerrit ;

Herrmann, Andreas ;

Muellen, Klaus ;

Hagfeldt, Anders .

JOURNAL OF PHYSICAL CHEMISTRY C, 2007, 111 (42) :15137-15140

[8] NEAR-INFRARED ABSORBING DYES [J].

FABIAN, J ;

NAKAZUMI, H ;

MATSUOKA, M .

CHEMICAL REVIEWS, 1992, 92 (06) :1197-1226

[9] Facile oxidative rearrangement of dispiro-porphodimethenes to nonplanar and sheetlike porphyrins with intense absorptions in the near-IR region [J].

Gill, HS ;

Harmjanz, M ;

Santamaría, J ;

Finger, I ;

Scott, MJ .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (04) :485-490

[10] LIGHT-INDUCED REDOX REACTIONS IN NANOCRYSTALLINE SYSTEMS [J].

HAGFELDT, A ;

GRATZEL, M .

CHEMICAL REVIEWS, 1995, 95 (01) :49-68

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