Design of Dimeric Dinuclear Boron Complexes with Flexible Linkers: Aggregation-induced White-light Emission via Molecular Engineering

被引:8
|
作者
Ihara, Megumi [1 ]
Cui, Luxia [1 ]
Konishi, Yuto [1 ]
Hisaeda, Yoshio [1 ,2 ]
Ono, Toshikazu [1 ,2 ]
机构
[1] Kyushu Univ, Grad Sch Engn, Dept Chem & Biochem, Nishi Ku, 744 Motooka, Fukuoka 8190395, Japan
[2] Kyushu Univ, Ctr Mol Syst CMS, Nishi Ku, 744 Motooka, Fukuoka 8190395, Japan
关键词
Boron complexes; White-light emission; Aggregation; BODIPY DYES; CRYSTALS; FLUORESCENT; PATHWAYS;
D O I
10.1246/cl.210794
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The aggregation state of two new covalently bonded dinuclear boron-based dye complexes was controlled to fabricate white-light-emitting materials. The materials exhibit blue and orange emission, with a photoluminescence quantum yield of 16% for one of the complexes in the solid state. This study highlights the importance of molecular engineering through the control of dye aggregation as a fundamental technology for creating novel functional materials with interesting optical properties.
引用
收藏
页码:300 / 302
页数:3
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