Experimental measurements and predictions of dissociation conditions for methane, ethane, propane, and carbon dioxide simple hydrates in the presence of diethylene glycol aqueous solutions

被引:40
作者
Afzal, Waheed [1 ]
Mohammadi, Amir H. [1 ]
Richon, Dominique [1 ]
机构
[1] CNRS, FRE 2861, CEP TEP, Mines Paris,ParisTech, F-77305 Fontainebleau, France
关键词
D O I
10.1021/je700457r
中图分类号
O414.1 [热力学];
学科分类号
摘要
Experimental gas hydrate dissociation data for methane + 0.066 and 0.168 mass fractions diethylene glycol aqueous solution, ethane + 0.071 and 0.163 mass fractions diethylene glycol aqueous solution, propane + 0.073 and 0.164 mass fractions diethylene glycol aqueous solution, and carbon dioxide + 0.074 and 0.163 mass fractions diethylene glycol aqueous solution systems are reported herein. The new experimental data have been measured using an isochoric method. All the experimental data are compared with the predictions of a general correlation and a thermodynamic model, and the agreements between the experimental and predicted data are found to be generally acceptable.
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收藏
页码:663 / 666
页数:4
相关论文
共 10 条
  • [1] Experimental measurements and predictions of dissociation conditions for carbon dioxide and methane hydrates in the presence of triethylene glycol aqueous solutions
    Afkal, Waheed
    Mohammadi, Amir H.
    Richon, Dominique
    [J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2007, 52 (05) : 2053 - 2055
  • [2] PREDICTION OF VL AND VLL EQUILIBRIA OF MIXTURES CONTAINING PETROLEUM RESERVOIR FLUIDS AND METHANOL WITH A CUBIC EOS
    AVLONITIS, D
    DANESH, A
    TODD, AC
    [J]. FLUID PHASE EQUILIBRIA, 1994, 94 : 181 - 216
  • [3] Avlonitis D.A., 1992, THESIS HERIOT WATT U
  • [4] Clathrate hydrate formed with methane and 2-Propanol: Confirmation of structure II hydrate formation
    Ohmura, R
    Takeya, S
    Uchida, T
    Ebinuma, T
    [J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2004, 43 (16) : 4964 - 4966
  • [5] A general correlation for predicting the suppression of hydrate dissociation temperature in the presence of thermodynamic inhibitors
    Ostergaard, KK
    Masoudi, R
    Tohidi, B
    Danesh, A
    Todd, AC
    [J]. JOURNAL OF PETROLEUM SCIENCE AND ENGINEERING, 2005, 48 (1-2) : 70 - 80
  • [6] Sloan E. D., 1998, CLATHRATE HYDRATES N
  • [7] Tohidi B, 2000, ANN NY ACAD SCI, V912, P924
  • [8] Tohidi-Kalorazi B., 1995, THESIS HERIOT WATT U
  • [9] A GENERALIZED PATEL-TEJA EQUATION OF STATE FOR POLAR AND NONPOLAR FLUIDS AND THEIR MIXTURES
    VALDERRAMA, JO
    [J]. JOURNAL OF CHEMICAL ENGINEERING OF JAPAN, 1990, 23 (01) : 87 - 91
  • [10] VANDERWAALS JH, 1959, ADV CHEM PHYS, V2, P1