Phosphane-Pyridine Iron Complexes: Synthesis, Characterization and Application in Reductive Amination through the Hydrosilylation Reaction

被引：51

作者：

Jaafar, Hassen ^{[1
]}

Li, Haoquan ^{[1
]}

Castro, Luis C. Misal ^{[1
]}

Zheng, Jianxia ^{[1
]}

Roisnel, Thierry ^{[2
]}

Dorcet, Vincent ^{[2
]}

Sortais, Jean-Baptiste ^{[1
]}

Darcel, Christophe ^{[1
]}

机构：

[1] Univ Rennes 1, UMR CNRS 6226, Inst Sci Chim Rennes Organometall Mat & Catalysis, F-35042 Rennes, France

[2] Univ Rennes 1, UMR CNRS 6226, Inst Sci Chim Rennes, Ctr Diffractometrie 10, F-35042 Rennes, France

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2012年 / 22期

关键词：

Iron; Homogeneous catalysis; Hydrosilylation; Amination; ORGANOMETALLIC TRIDENTATE LIGAND; EFFICIENT HYDROSILYLATION; COORDINATION CHEMISTRY; CARBONYL-COMPOUNDS; AMINES; ALDEHYDES; CATALYST; KETONES; FE; ALKYLATION;

D O I：

10.1002/ejic.201200550

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of 6 cyclopentadienyl phosphanyl-pyridine piano-stool iron complexes was prepared in good yields, characterized, and studied in the catalytic reductive amination of benzaldehyde derivatives through hydrosilylation reactions by using polymethylhydrosiloxane as the hydrosilane source and in dimethylcarbonate as the solvent at 40 degrees C. Single-crystal X-ray structural analyses were performed for all the complexes.

引用

页码：3546 / 3550

页数：5

共 61 条

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