Measurement of high pressure densities and atmospheric pressure viscosities of alkyl phosphate anion ionic liquids and correlation with the ε*-modified Sanchez-Lacombe equation of state

被引：18
作者：
Hiraga, Yuya [1 ]
Goto, Musashi [2 ]
Sato, Yoshiyuki [1 ]
Smith, Richard L., Jr. [1 ,2 ]
机构：
[1] Tohoku Univ, Res Ctr Supercrit Fluid Technol, Aoba Ku, Aramaki Aza Aoba 6-6-11, Sendai, Miyagi 9808579, Japan
[2] Tohoku Univ, Grad Sch Environm Studies, Aoba Ku, Aramaki Aza Aoba 6-6-11, Sendai, Miyagi 9808579, Japan
来源：
JOURNAL OF CHEMICAL THERMODYNAMICS | 2017年 / 104卷
关键词：
Ionic liquid; Density; Viscosity; Equation of state; VOLUMETRIC PROPERTIES; 1-ETHYL-3-METHYLIMIDAZOLIUM ETHYLSULFATE; LIGNOCELLULOSIC BIOMASS; CARBON-DIOXIDE; 200; MPA; DISSOLUTION; CELLULOSE; TEMPERATURE; BIS(TRIFLUOROMETHYLSULFONYL)IMIDE; METHYLSULFATE;
D O I：
10.1016/j.jct.2016.09.013
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
High pressure densities up to 200 MPa from 313 to 393 K and atmospheric pressure viscosities from 293 to 373 K for two alkyl phosphate anion ionic liquids, 1-ethyl-3-methylimidazolium dimethylphosphate ([emim][DMP]) and 1-butyl-3-methylimidazolium dimethylphosphate ([ bmim][DMP]), are reported. Several forms of the Tait equation were applied and all forms could correlate the data to within 0.03% average relative deviation (ARD). The derivative properties calculated had specific trends for the ionic liquids. The epsilon*-modified Sanchez-Lacombe equation of state could correlate the data to within an ARD of 0.07%, and the deviations were lower than those of the original Sanchez-Lacombe equation of state (0.19%). The improvement by epsilon*-modified Sanchez-Lacombe equation of state can be attributed its assumed close-packed density structure at low temperature. (C) 2016 Elsevier Ltd.
引用
收藏
页码：73 / 81
页数：9
相关论文
共 53 条
  • [41] Correlation of molecular structure and polarity of ionic liquids
    Spange, Stefan
    Lungwitz, Ralf
    Schade, Alexander
    [J]. JOURNAL OF MOLECULAR LIQUIDS, 2014, 192 : 137 - 143
  • [42] Solubility of carbon dioxide, nitrous oxide, ethane, and nitrogen in 1-butyl-1-methylpyrrolidinium and trihexyl(tetradecyl)phosphonium tris(pentafluoroethyl)trifluorophosphate (eFAP) ionic liquids
    Stevanovic, S.
    Gomes, M. F. Costa
    [J]. JOURNAL OF CHEMICAL THERMODYNAMICS, 2013, 59 : 65 - 71
  • [43] Effect of Water on the Carbon Dioxide Absorption by 1-Alkyl-3-methylimidazolium Acetate Ionic Liquids
    Stevanovic, Stephane
    Podgorsek, Ajda
    Padua, Agilio A. H.
    Gomes, Margarida F. Costa
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2012, 116 (49) : 14416 - 14425
  • [44] High-Pressure Densities of 1-Alkyl-3-methylimidazolium Hexafluorophosphates and 1-Alkyl-3-methylimidazolium Tetrafluoroborates at Temperatures from (313 to 473) K and at Pressures up to 200 MPa
    Taguchi, Ryosuke
    Machida, Hiroshi
    Sato, Yoshiyuki
    Smith, Richard L., Jr.
    [J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2009, 54 (01) : 22 - 27
  • [45] Measurements and correlation of high-pressure densities of imidazolium-based ionic liquids
    Tome, Luciana I. N.
    Carvalho, Pedro J.
    Freire, Mara G.
    Marrucho, Isabel M.
    Fonseca, Isabel M. A.
    Ferreira, Abel G. M.
    Coutinho, Joao A. P.
    Gardas, Ramesh L.
    [J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2008, 53 (08) : 1914 - 1921
  • [46] Measurements and Correlation of High-Pressure Densities of Phosphonium Based Ionic Liquids
    Tome, Luciana I. N.
    Gardas, Ramesh L.
    Carvalho, Pedro J.
    Jose Pastoriza-Gallego, Maria
    Pineiro, Manuel M.
    Coutinho, Joao A. P.
    [J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2011, 56 (05) : 2205 - 2217
  • [47] Extended dissolution studies of cellulose in imidazolium based ionic liquids
    Vitz, Jurgen
    Erdmenger, Tina
    Haensch, Claudia
    Schubert, Ulrich S.
    [J]. GREEN CHEMISTRY, 2009, 11 (03) : 417 - 424
  • [48] Wang M., 2013, ADV MAT RES, V800, P106
  • [49] Widjaja A., 2015, B CHEM REACT ENG CAT, V10
  • [50] Enzymatic in situ saccharification of rice straw in aqueous-ionic liquid media using encapsulated Trichoderma aureoviride cellulase
    Xu, Jiaxing
    Liu, Xiaoyan
    He, Jianlong
    Hu, Lei
    Dai, Benlin
    Wu, Bin
    [J]. JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY, 2015, 90 (01) : 57 - 63
123456