Measurement of high pressure densities and atmospheric pressure viscosities of alkyl phosphate anion ionic liquids and correlation with the ε*-modified Sanchez-Lacombe equation of state

被引：18
作者：
Hiraga, Yuya [1 ]
Goto, Musashi [2 ]
Sato, Yoshiyuki [1 ]
Smith, Richard L., Jr. [1 ,2 ]
机构：
[1] Tohoku Univ, Res Ctr Supercrit Fluid Technol, Aoba Ku, Aramaki Aza Aoba 6-6-11, Sendai, Miyagi 9808579, Japan
[2] Tohoku Univ, Grad Sch Environm Studies, Aoba Ku, Aramaki Aza Aoba 6-6-11, Sendai, Miyagi 9808579, Japan
来源：
JOURNAL OF CHEMICAL THERMODYNAMICS | 2017年 / 104卷
关键词：
Ionic liquid; Density; Viscosity; Equation of state; VOLUMETRIC PROPERTIES; 1-ETHYL-3-METHYLIMIDAZOLIUM ETHYLSULFATE; LIGNOCELLULOSIC BIOMASS; CARBON-DIOXIDE; 200; MPA; DISSOLUTION; CELLULOSE; TEMPERATURE; BIS(TRIFLUOROMETHYLSULFONYL)IMIDE; METHYLSULFATE;
D O I：
10.1016/j.jct.2016.09.013
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
High pressure densities up to 200 MPa from 313 to 393 K and atmospheric pressure viscosities from 293 to 373 K for two alkyl phosphate anion ionic liquids, 1-ethyl-3-methylimidazolium dimethylphosphate ([emim][DMP]) and 1-butyl-3-methylimidazolium dimethylphosphate ([ bmim][DMP]), are reported. Several forms of the Tait equation were applied and all forms could correlate the data to within 0.03% average relative deviation (ARD). The derivative properties calculated had specific trends for the ionic liquids. The epsilon*-modified Sanchez-Lacombe equation of state could correlate the data to within an ARD of 0.07%, and the deviations were lower than those of the original Sanchez-Lacombe equation of state (0.19%). The improvement by epsilon*-modified Sanchez-Lacombe equation of state can be attributed its assumed close-packed density structure at low temperature. (C) 2016 Elsevier Ltd.
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页码：73 / 81
页数：9
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共 53 条
  • [1] Understanding the polarity of ionic liquids
    Ab Rani, M. A.
    Brant, A.
    Crowhurst, L.
    Dolan, A.
    Lui, M.
    Hassan, N. H.
    Hallett, J. P.
    Hunt, P. A.
    Niedermeyer, H.
    Perez-Arlandis, J. M.
    Schrems, M.
    Welton, T.
    Wilding, R.
    [J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2011, 13 (37) : 16831 - 16840
  • [2] Nucleic acid bases in 1-alkyl-3-methylimidazolium acetate ionic liquids: A thermophysical and ionic conductivity analysis
    Araujo, J. M. M.
    Pereiro, A. B.
    Alves, F.
    Marrucho, I. M.
    Rebelo, L. P. N.
    [J]. JOURNAL OF CHEMICAL THERMODYNAMICS, 2013, 57 : 1 - 8
  • [3] Factors governing dissolution process of lignocellulosic biomass in ionic liquid: Current status, overview and challenges
    Badgujar, Kirtikumar C.
    Bhanage, Bhalchandra M.
    [J]. BIORESOURCE TECHNOLOGY, 2015, 178 : 2 - 18
  • [4] Experimental investigation of ionic liquid pretreatment of sugarcane bagasse with 1,3-dimethylimadazolium dimethyl phosphate
    Bahrani, Samaneh
    Raeissi, Sona
    Sarshar, Mohammad
    [J]. BIORESOURCE TECHNOLOGY, 2015, 185 : 411 - 415
  • [5] Deconstruction of lignocellulosic biomass with ionic liquids
    Brandt, Agnieszka
    Grasvik, John
    Hallett, Jason P.
    Welton, Tom
    [J]. GREEN CHEMISTRY, 2013, 15 (03) : 550 - 583
  • [6] The effect of the ionic liquid anion in the pretreatment of pine wood chips
    Brandt, Agnieszka
    Hallett, Jason P.
    Leak, David J.
    Murphy, Richard J.
    Welton, Tom
    [J]. GREEN CHEMISTRY, 2010, 12 (04) : 672 - 679
  • [7] Modeling of the volumetric properties and estimation of the solubility parameters of ionic liquid plus ethanol mixtures with the Sanchez-Lacombe and Simha-Somcynsky equations of state: [EMIM]Ac plus ethanol and [EMIM]Cl plus ethanol mixtures
    Dickmann, James S.
    Hassler, John C.
    Kiran, Erdogan
    [J]. JOURNAL OF SUPERCRITICAL FLUIDS, 2015, 98 : 86 - 101
  • [8] STUDIES IN NEWTONIAN FLOW .2. THE DEPENDENCE OF THE VISCOSITY OF LIQUIDS ON FREE-SPACE
    DOOLITTLE, AK
    [J]. JOURNAL OF APPLIED PHYSICS, 1951, 22 (12) : 1471 - 1475
  • [9] THE TAIT EQUATION - 100 YEARS ON
    DYMOND, JH
    MALHOTRA, R
    [J]. INTERNATIONAL JOURNAL OF THERMOPHYSICS, 1988, 9 (06) : 941 - 951
  • [10] Viscosities of Acetate or Chloride-Based Ionic Liquids and Some of Their Mixtures with Water or Other Common Solvents
    Fendt, Sebastian
    Padmanabhan, Sasisanker
    Blanch, Harvey W.
    Prausnitz, John M.
    [J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2011, 56 (01) : 31 - 34
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