Metal-Free Direct Hydrosulfonylation of Azodicarboxylates with Sulfinic Acids Leading to Sulfonylhydrazine Derivatives

被引：13

作者：

Wen, Jiangwei

Wei, Wei ^{[1
]}

Yang, Daoshan

Fan, Yufeng

Fu, Lulu

Wang, Hua

机构：

[1] Qufu Normal Univ, Key Lab Life Organ Anal, Sch Chem & Chem Engn, Qufu 273165, Shandong, Peoples R China

来源：

SYNTHETIC COMMUNICATIONS | 2015年 / 45卷 / 13期

基金：

中国国家自然科学基金;

关键词：

Hydrosulfonylation; metal-free; sulfinic acids; sulfonylhydrazine-1; 2-dicarboxylates; CATALYZED ALLYLIC SULFONYLATION; AEROBIC DIFUNCTIONALIZATION; HIGHLY EFFICIENT; SULFUR-DIOXIDE; C-S; ALKENES; AMINOSULFONYLATION; ARYLSULFONYLATION; INHIBITION; VNP40101M;

D O I：

10.1080/00397911.2015.1034871

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A metal-free direct hydrosulfonylation protocol of azodicarboxylates with sulfinic acids has been developed for the construction of sulfonylhydrazine-1,2-dicarboxylates at room temperature. This methodology provides an efficient and practical approach to prepare various sulfonylhydrazine-1,2-dicarboxylates in good to excellent yields, which has the advantages of operation simplicity, environmental friendliness, high atom economy, and mild reaction conditions.

引用

页码：1574 / 1584

页数：11

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