Co-liquefaction of Prosopis juliflora with polyolefin waste for production of high grade liquid hydrocarbons

被引:47
作者
Arun, Jayaseelan [1 ]
Gopinath, Kannappan Panchamoorthy [1 ]
SundarRajan, PanneerSelvam [1 ]
JoselynMonica, Marudai [1 ]
Felix, Vargees [1 ]
机构
[1] SSN Coll Engn, Dept Chem Engn, Thiruporur 603110, Tamil Nadu, India
关键词
Polyolefin; Prosopis juliflora; Hydrothermal liquefaction; Bio-oil; HTL wastewater; HYDROTHERMAL LIQUEFACTION; BIO-OIL; CATALYTIC PYROLYSIS; BIOMASS; CONVERSION; LIGNIN; TEMPERATURE; TECHNOLOGY; CELLULOSE; RESIDUES;
D O I
10.1016/j.biortech.2018.11.102
中图分类号
S2 [农业工程];
学科分类号
0828 ;
摘要
In this study, co-liquefaction (HTL) of Prosopis juliflora (PJ) biomass with polyolefin waste (PO) was performed to produce bio-oil. HTL on bio-oil yield was studied at varying PJ to PO ratios (0:1, 1:0, 1:1, 2:1, 3:1, 4:1 and 5:1) and temperatures from 340 to 440 degrees C. Bio-oil and HTL by-products were characterized by Mass Spectroscopy (GC-MS) and Fourier Transform Infrared Spectroscopy (FTIR) analysis. Bio-oil yield was around 61.23%wt at 420 degrees C for 3:1 blends with 3 wt% of HCl activated bentonite catalyst at 60 min holding time. HHV value was 46 MJ/Kg with 88.23% purity (petro-diesel). Additionally gas possessed 26.28% of Hydrogen gas, 45.59% of Carbon dioxide gas, 7.1% of Carbon monoxide gas, 8.12% of Methane gas and other elements. The energy recovery (78%) and carbon recovery (94%) was higher for 3:1 blends bio-oil than PO and PJ processed bio-oils. HTL wastewater possessed higher degree of reusability nature as HTL medium.
引用
收藏
页码:296 / 301
页数:6
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