CH/π attraction:: The origin of enantioselectivity in transfer hydrogenation of aromatic carbonyl compounds catalyzed by chiral η6-arene-ruthenium(II) complexes

被引：0
作者：
Yamakawa, M
Yamada, I
Noyori, R [1 ]
机构：
[1] Nagoya Univ, Dept Chem, Chikusa Ku, Nagoya, Aichi 4648602, Japan
[2] Nagoya Univ, Res Ctr Mat Sci, Chikusa Ku, Nagoya, Aichi 4648602, Japan
[3] Kinjo Gakuin Univ, Nagoya, Aichi 4638521, Japan
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2001年 / 40卷 / 15期
关键词：
asymmetric synthesis; CH/pi interactions; density functional calculations; hydrogenation; ruthenium;
D O I：
10.1002/1521-3773(20010803)40:15<2818::AID-ANIE2818>3.0.CO;2-Y
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The through-space CH/π attraction between the η6-arene ligand on Ru and the carbonyl aryl substituent (see transition states in picture) plays a key role in the enantioselective transfer hydrogenation of aromatic carbonyl compounds with 2-propanol or formic acid, catalyzed by chiral η6-arene-RuII complexes.
引用
收藏
页码：2818 / 2821
页数：4
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